TY  - JOUR
AU  - Vasiljević, Zorka Z
AU  - Vunduk, Jovana
AU  - Dojčinović, Milena
AU  - Mišković, Goran
AU  - Tadic, Nenad
AU  - Vidic, Jasmina
AU  - Nikolić, Maria Vesna
PY  - 2024
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/3190
AB  - In this paper, we have systematically studied the structural, morphological, and optical properties of Ni-doped TiO2, synthesized via a simple, cost-effective electrospinning method followed by calcination at 500 C. The nanofibers with a core-shell structure were relatively homogeneous, smooth and randomly oriented, and there were no significant differences in fiber diameters due to Ni2+ content. Core loss mapping using electron energy loss spectroscopy confirmed an even distribution of titanium and relatively uniform nickel in the fibers. It was found that doping with 0.5 mol.% Ni2+ decreased the rutile content, while doping with 1 mol.% Ni2+ resulted in a pure anatase phase with a significantly increased specific surface area (36.6 m2/g). Further increase in Ni2+ content (3-10 mol.%) not only prolonged the response of TiO2 nanofibers to visible light, but also increased the specific surface area (49.5 m2/g), decreased crystallite size (7 nm), and increased rutile content in TiO2 (33 wt.%). Photoluminescence analysis revealed that doping TiO2 with different amounts of Ni2+ leads to a gradual decrease of emission spectra intensity and red shift in the maxima positions. The XPS results confirmed that as the Ni2+ content enlarged, the Ti2+ and Ti3+ content increased significantly, effectively promoting the formation of oxygen vacancies. Raman analysis showed that an increase in nickel content (3-5 mol.%) led to a decrease and shift in peak intensity due to Ti3+ formation and also the possible presence of NiTiO3 phases. HRTEM analysis showed that Ni was doped into the substitution sites of both the anatase and rutile TiO2 lattice but had a stronger influence on the distortion of the anatase phase. The obtained results indicate that Ni-doped TiO2 nanofibers are good candidates for photocatalytic applications.
PB  - Elsevier
T2  - Food Packaging and Shelf Life
T1  - ZnO and Fe2TiO5 Nanoparticles Obtained by Green Synthesis as Active Components of Alginate Food Packaging Films
SP  - 101280
VL  - 43
DO  - 10.1016/j.fpsl.2024.101280
ER  - 

@article{
author = "Vasiljević, Zorka Z and Vunduk, Jovana and Dojčinović, Milena and Mišković, Goran and Tadic, Nenad and Vidic, Jasmina and Nikolić, Maria Vesna",
year = "2024",
abstract = "In this paper, we have systematically studied the structural, morphological, and optical properties of Ni-doped TiO2, synthesized via a simple, cost-effective electrospinning method followed by calcination at 500 C. The nanofibers with a core-shell structure were relatively homogeneous, smooth and randomly oriented, and there were no significant differences in fiber diameters due to Ni2+ content. Core loss mapping using electron energy loss spectroscopy confirmed an even distribution of titanium and relatively uniform nickel in the fibers. It was found that doping with 0.5 mol.% Ni2+ decreased the rutile content, while doping with 1 mol.% Ni2+ resulted in a pure anatase phase with a significantly increased specific surface area (36.6 m2/g). Further increase in Ni2+ content (3-10 mol.%) not only prolonged the response of TiO2 nanofibers to visible light, but also increased the specific surface area (49.5 m2/g), decreased crystallite size (7 nm), and increased rutile content in TiO2 (33 wt.%). Photoluminescence analysis revealed that doping TiO2 with different amounts of Ni2+ leads to a gradual decrease of emission spectra intensity and red shift in the maxima positions. The XPS results confirmed that as the Ni2+ content enlarged, the Ti2+ and Ti3+ content increased significantly, effectively promoting the formation of oxygen vacancies. Raman analysis showed that an increase in nickel content (3-5 mol.%) led to a decrease and shift in peak intensity due to Ti3+ formation and also the possible presence of NiTiO3 phases. HRTEM analysis showed that Ni was doped into the substitution sites of both the anatase and rutile TiO2 lattice but had a stronger influence on the distortion of the anatase phase. The obtained results indicate that Ni-doped TiO2 nanofibers are good candidates for photocatalytic applications.",
publisher = "Elsevier",
journal = "Food Packaging and Shelf Life",
title = "ZnO and Fe2TiO5 Nanoparticles Obtained by Green Synthesis as Active Components of Alginate Food Packaging Films",
pages = "101280",
volume = "43",
doi = "10.1016/j.fpsl.2024.101280"
}

Vasiljević, Z. Z., Vunduk, J., Dojčinović, M., Mišković, G., Tadic, N., Vidic, J.,& Nikolić, M. V.. (2024). ZnO and Fe2TiO5 Nanoparticles Obtained by Green Synthesis as Active Components of Alginate Food Packaging Films. in Food Packaging and Shelf Life
Elsevier., 43, 101280.
https://doi.org/10.1016/j.fpsl.2024.101280

Vasiljević ZZ, Vunduk J, Dojčinović M, Mišković G, Tadic N, Vidic J, Nikolić MV. ZnO and Fe2TiO5 Nanoparticles Obtained by Green Synthesis as Active Components of Alginate Food Packaging Films. in Food Packaging and Shelf Life. 2024;43:101280.
doi:10.1016/j.fpsl.2024.101280 .

Vasiljević, Zorka Z, Vunduk, Jovana, Dojčinović, Milena, Mišković, Goran, Tadic, Nenad, Vidic, Jasmina, Nikolić, Maria Vesna, "ZnO and Fe2TiO5 Nanoparticles Obtained by Green Synthesis as Active Components of Alginate Food Packaging Films" in Food Packaging and Shelf Life, 43 (2024):101280,
https://doi.org/10.1016/j.fpsl.2024.101280 . .

TY  - CONF
AU  - Dojčinović, Milena
AU  - Vasiljević, Zorka Z
AU  - Tadic, Nenad
AU  - Krstic, Jugoslav
AU  - Nikolić, Maria Vesna
PY  - 2022
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1617
AB  - Transition metal oxides (TMOs) are promising materials because of their specific properties enabling their application in energy solutions, such as their pseudocapacitive behavior enabling utilization as electrode materials in supercapacitors. Activated carbon is a material well known as an electric double layer capacitor (EDLC). Bringing together the two different capacitor materials- TMOs as pseudocapacitors and carbon materials as EDL capacitors is the goal for generating future generation supercapacitors. Nickel manganite is a material of interest because of various oxidation states of manganese which provide its reactivity in oxidoreduction reactions, enhancing the pseudocapacitive behavior. Herein, we synthesized nano-sized nickel manganite by a sol-gel combustion synthesis process using glycine as fuel and subsequent calcination process. The structure and morphology of synthesized material was investigated via XRD, FESEM, and FTIR spectroscopy. Specific surface area and was determined from measured nitrogen 
 desorption/desorption isotherms. Activated carbon was obtained by pyrolytic carbonization of alginate hydrogel in nitrogen atmosphere and activation with KOH. The material was combined with synthesized NiMn2O4 nanopowder and tested as supercapacitor electrode. The second alternative was incorporating NiMn2O4 powder into alginate hydrogel, followed by pyrolysis in nitrogen atmosphere to obtain a NiMn2O4 -activated
carbon composite. The obtained materials were electrochemically characterized with cyclic voltammetry (LV) and galvanostatic chronopotentiometry to get galvanostatic charge-discharge curves. We calculated high specific capacitance values ranging to several hundred F/g, showing our hybrid material is a promising electrode in a supercapacitor system.
PB  - Krakow : Agencja Reklamowa EURO GRAPHIC
PB  - Krakow : Polskie Towarzystwo Ceramiczne
C3  - Abstract Book / Ceramics in Europe 2022, Krakow, 10-14 July, 2022
T1  - Alginate-derived activated carbon hybridized with NiMn2O4 for use in supercapacitors
SP  - 404
UR  - https://hdl.handle.net/21.15107/rcub_rimsi_1617
ER  - 

@conference{
author = "Dojčinović, Milena and Vasiljević, Zorka Z and Tadic, Nenad and Krstic, Jugoslav and Nikolić, Maria Vesna",
year = "2022",
abstract = "Transition metal oxides (TMOs) are promising materials because of their specific properties enabling their application in energy solutions, such as their pseudocapacitive behavior enabling utilization as electrode materials in supercapacitors. Activated carbon is a material well known as an electric double layer capacitor (EDLC). Bringing together the two different capacitor materials- TMOs as pseudocapacitors and carbon materials as EDL capacitors is the goal for generating future generation supercapacitors. Nickel manganite is a material of interest because of various oxidation states of manganese which provide its reactivity in oxidoreduction reactions, enhancing the pseudocapacitive behavior. Herein, we synthesized nano-sized nickel manganite by a sol-gel combustion synthesis process using glycine as fuel and subsequent calcination process. The structure and morphology of synthesized material was investigated via XRD, FESEM, and FTIR spectroscopy. Specific surface area and was determined from measured nitrogen 
 desorption/desorption isotherms. Activated carbon was obtained by pyrolytic carbonization of alginate hydrogel in nitrogen atmosphere and activation with KOH. The material was combined with synthesized NiMn2O4 nanopowder and tested as supercapacitor electrode. The second alternative was incorporating NiMn2O4 powder into alginate hydrogel, followed by pyrolysis in nitrogen atmosphere to obtain a NiMn2O4 -activated
carbon composite. The obtained materials were electrochemically characterized with cyclic voltammetry (LV) and galvanostatic chronopotentiometry to get galvanostatic charge-discharge curves. We calculated high specific capacitance values ranging to several hundred F/g, showing our hybrid material is a promising electrode in a supercapacitor system.",
publisher = "Krakow : Agencja Reklamowa EURO GRAPHIC, Krakow : Polskie Towarzystwo Ceramiczne",
journal = "Abstract Book / Ceramics in Europe 2022, Krakow, 10-14 July, 2022",
title = "Alginate-derived activated carbon hybridized with NiMn2O4 for use in supercapacitors",
pages = "404",
url = "https://hdl.handle.net/21.15107/rcub_rimsi_1617"
}

Dojčinović, M., Vasiljević, Z. Z., Tadic, N., Krstic, J.,& Nikolić, M. V.. (2022). Alginate-derived activated carbon hybridized with NiMn2O4 for use in supercapacitors. in Abstract Book / Ceramics in Europe 2022, Krakow, 10-14 July, 2022
Krakow : Agencja Reklamowa EURO GRAPHIC., 404.
https://hdl.handle.net/21.15107/rcub_rimsi_1617

Dojčinović M, Vasiljević ZZ, Tadic N, Krstic J, Nikolić MV. Alginate-derived activated carbon hybridized with NiMn2O4 for use in supercapacitors. in Abstract Book / Ceramics in Europe 2022, Krakow, 10-14 July, 2022. 2022;:404.
https://hdl.handle.net/21.15107/rcub_rimsi_1617 .

Dojčinović, Milena, Vasiljević, Zorka Z, Tadic, Nenad, Krstic, Jugoslav, Nikolić, Maria Vesna, "Alginate-derived activated carbon hybridized with NiMn2O4 for use in supercapacitors" in Abstract Book / Ceramics in Europe 2022, Krakow, 10-14 July, 2022 (2022):404,
https://hdl.handle.net/21.15107/rcub_rimsi_1617 .