@article{
author = "Begović, Nebojša N. and Vasić, Milica and Blagojevic, Vladimir and Filipović, Nenad and Marinković, Aleksandar and Malešević, Aleksandar and Minic, Dragica",
year = "2017",
abstract = "The structure of new cis-dichloro[(E)-ethyl-2-(2-
((8-hydroxyquinolin-2-il)methylene)hidrazinyl)acetate-j2N]-
palladium(II) complex was determined using a combination
of XRD and IR measurements and DFT calculations.
Inherent flexibility of its structure is evident from the complexity
of its IR spectrum, which could only be theoretically
reproduced as a combination of several closely related
structures, involving rotation around C–O bond and changes
in hydrogen interactions of its –OH group. Its thermal stability
and decomposition were studied non-isothermally, and
the thermal decomposition mechanism was proposed using
correlation with DFT calculations at the molecular level. It
was determined that the initial degradation step consists of
the release of Cl free radical, which then reacts with both the
initial compound and the degradation products. Besides the
endothermic steps, there are exothermic ones, contributing to
the complex shape of the DSC curve, consisted of overlapping
endothermic and exothermic peaks. Deconvolution of
DTG curve allowed identification of primary fragments of
the initial degradation process and, in conjunction with DFT
calculations, construction of the most likely reaction
mechanism.",
publisher = "Springer Science & Business Media, Akadémiai Kiadó",
journal = "Journal of Thermal Analysis and Calorimetry",
title = "Synthesis and thermal stability of cis-dichloro[(E)-ethyl-2-(2-((8- hydroxyquinolin-2-il)methylene)hidrazinyl)acetate-κ2N]-palladium(II) complex",
pages = "711-701",
volume = "130",
doi = "10.1007/s10973-017-6458-2"
}
