Krstajic Pajic, Mila

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Ultra-low Pt loading catalyst on (Nb–Ti)2AlC support as advanced material for low-temperature fuel cell application

Petričević, Aleksandar; Jović, Vladimir D; Krstajic Pajic, Mila; Marzec, M.; Gajevska, M.; Zabinski, Piotr; Elezović, Nevenka R.

(Taylor and Francis, 2023)

TY  - JOUR
AU  - Petričević, Aleksandar
AU  - Jović, Vladimir D
AU  - Krstajic Pajic, Mila
AU  - Marzec, M.
AU  - Gajevska, M.
AU  - Zabinski, Piotr
AU  - Elezović, Nevenka R.
PY  - 2023
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/2341
AB  - The oxygen reduction reaction was investigated at 10 monolayers (MLs) of Pt electrodeposited on (Nb–Ti)2AlC substrate. Following the discussion of detailed kinetics and electrodeposition optimisation in the authors’ previous paper, the focus of this research was on stability testing. Previously performed optimisation results showed the best activity shown by 10 monolayers of Pt. Catalyst characterisation was performed by scanning electron microscopy, X-ray photoelectron spectroscopy and transmission electron microscopy. SEM, EDS and XPS analysis showed that the surface was covered with a homogeneous layer of Pt. TEM analysis of a cross-section confirmed the presence of Pt layer of thickness ∼3.5 nm, corresponding to the 10 MLs of Pt. Although the mass activity for the ORR at 0.8 V vs. RHE of 37.4 A g−1 was comparable with the best one for the Pt/C benchmark, US Department of Energy Protocols revealed excellent catalyst stability – the loss of electrochemically active surface area (EASA) was found to be only 9.3%.
PB  - Taylor and Francis
T2  - Transactions of the IMF
T1  - Ultra-low Pt loading catalyst on (Nb–Ti)2AlC support as advanced material for low-temperature fuel cell application
DO  - 10.1080/00202967.2023.2281806
ER  - 
@article{
author = "Petričević, Aleksandar and Jović, Vladimir D and Krstajic Pajic, Mila and Marzec, M. and Gajevska, M. and Zabinski, Piotr and Elezović, Nevenka R.",
year = "2023",
abstract = "The oxygen reduction reaction was investigated at 10 monolayers (MLs) of Pt electrodeposited on (Nb–Ti)2AlC substrate. Following the discussion of detailed kinetics and electrodeposition optimisation in the authors’ previous paper, the focus of this research was on stability testing. Previously performed optimisation results showed the best activity shown by 10 monolayers of Pt. Catalyst characterisation was performed by scanning electron microscopy, X-ray photoelectron spectroscopy and transmission electron microscopy. SEM, EDS and XPS analysis showed that the surface was covered with a homogeneous layer of Pt. TEM analysis of a cross-section confirmed the presence of Pt layer of thickness ∼3.5 nm, corresponding to the 10 MLs of Pt. Although the mass activity for the ORR at 0.8 V vs. RHE of 37.4 A g−1 was comparable with the best one for the Pt/C benchmark, US Department of Energy Protocols revealed excellent catalyst stability – the loss of electrochemically active surface area (EASA) was found to be only 9.3%.",
publisher = "Taylor and Francis",
journal = "Transactions of the IMF",
title = "Ultra-low Pt loading catalyst on (Nb–Ti)2AlC support as advanced material for low-temperature fuel cell application",
doi = "10.1080/00202967.2023.2281806"
}
Petričević, A., Jović, V. D., Krstajic Pajic, M., Marzec, M., Gajevska, M., Zabinski, P.,& Elezović, N. R.. (2023). Ultra-low Pt loading catalyst on (Nb–Ti)2AlC support as advanced material for low-temperature fuel cell application. in Transactions of the IMF
Taylor and Francis..
https://doi.org/10.1080/00202967.2023.2281806
Petričević A, Jović VD, Krstajic Pajic M, Marzec M, Gajevska M, Zabinski P, Elezović NR. Ultra-low Pt loading catalyst on (Nb–Ti)2AlC support as advanced material for low-temperature fuel cell application. in Transactions of the IMF. 2023;.
doi:10.1080/00202967.2023.2281806 .
Petričević, Aleksandar, Jović, Vladimir D, Krstajic Pajic, Mila, Marzec, M., Gajevska, M., Zabinski, Piotr, Elezović, Nevenka R., "Ultra-low Pt loading catalyst on (Nb–Ti)2AlC support as advanced material for low-temperature fuel cell application" in Transactions of the IMF (2023),
https://doi.org/10.1080/00202967.2023.2281806 . .