TY  - JOUR
AU  - Žunić, Milan
AU  - Chevallier, Laure
AU  - di Bartolomeo, Elisabetta
AU  - D'Epifanio, Alessandra
AU  - Licoccia, Silvia
AU  - Traversa, Enrico
PY  - 2011
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/486
AB  - Intermediate temperature solid oxide fuel cells (IT-SOFCs) were fabricated depositing proton conducting BaCe0.9Y0.1O3-x (BCY10) thick films on cermet substrates made of nickel oxide-yttrium doped barium cerate (NiO-BCY10) using electrophoretic deposition (EPD) technique. The influence of the EPD parameters on the microstructure and electrical properties of BCY10 thick films was investigated. Deposited BCY10 thick films together with green anode substrates were co-sintered in a single heating treatment at 1,550 degrees C for 2 h to obtain dense electrolyte and suitably porous anodes. The half-cells were characterised by field emission scanning electron microscopy (FE-SEM) and by X-ray diffraction (XRD) analysis. A composite cathode specifically developed for BCY electrolytes, made of La0.8Sr0.2Co0.8Fe0.2O3(LSCF, mixed oxygen-ion/electronic conductor) and BaCe0.9Yb0.1O3-delta (10YbBC, mixed protonic/electronic conductor), was used. Fuel cells were prepared by slurry coating the composite cathode on the co-sintered half-cells. Fuel cell tests and electrochemical impedance spectroscopy (EIS) were performed in the 550-700 degrees C temperature range. A maximum power density of 296 mW cm(-2) was achieved at 700 degrees C for electrolyte deposited at 60 V for 1 min.
PB  - Wiley-V C H Verlag Gmbh, Weinheim
T2  - Fuel Cells
T1  - Anode Supported Protonic Solid Oxide Fuel Cells Fabricated Using Electrophoretic Deposition
EP  - 171
IS  - 2
SP  - 165
VL  - 11
DO  - 10.1002/fuce.200900104
ER  - 

@article{
author = "Žunić, Milan and Chevallier, Laure and di Bartolomeo, Elisabetta and D'Epifanio, Alessandra and Licoccia, Silvia and Traversa, Enrico",
year = "2011",
abstract = "Intermediate temperature solid oxide fuel cells (IT-SOFCs) were fabricated depositing proton conducting BaCe0.9Y0.1O3-x (BCY10) thick films on cermet substrates made of nickel oxide-yttrium doped barium cerate (NiO-BCY10) using electrophoretic deposition (EPD) technique. The influence of the EPD parameters on the microstructure and electrical properties of BCY10 thick films was investigated. Deposited BCY10 thick films together with green anode substrates were co-sintered in a single heating treatment at 1,550 degrees C for 2 h to obtain dense electrolyte and suitably porous anodes. The half-cells were characterised by field emission scanning electron microscopy (FE-SEM) and by X-ray diffraction (XRD) analysis. A composite cathode specifically developed for BCY electrolytes, made of La0.8Sr0.2Co0.8Fe0.2O3(LSCF, mixed oxygen-ion/electronic conductor) and BaCe0.9Yb0.1O3-delta (10YbBC, mixed protonic/electronic conductor), was used. Fuel cells were prepared by slurry coating the composite cathode on the co-sintered half-cells. Fuel cell tests and electrochemical impedance spectroscopy (EIS) were performed in the 550-700 degrees C temperature range. A maximum power density of 296 mW cm(-2) was achieved at 700 degrees C for electrolyte deposited at 60 V for 1 min.",
publisher = "Wiley-V C H Verlag Gmbh, Weinheim",
journal = "Fuel Cells",
title = "Anode Supported Protonic Solid Oxide Fuel Cells Fabricated Using Electrophoretic Deposition",
pages = "171-165",
number = "2",
volume = "11",
doi = "10.1002/fuce.200900104"
}

Žunić, M., Chevallier, L., di Bartolomeo, E., D'Epifanio, A., Licoccia, S.,& Traversa, E.. (2011). Anode Supported Protonic Solid Oxide Fuel Cells Fabricated Using Electrophoretic Deposition. in Fuel Cells
Wiley-V C H Verlag Gmbh, Weinheim., 11(2), 165-171.
https://doi.org/10.1002/fuce.200900104

Žunić M, Chevallier L, di Bartolomeo E, D'Epifanio A, Licoccia S, Traversa E. Anode Supported Protonic Solid Oxide Fuel Cells Fabricated Using Electrophoretic Deposition. in Fuel Cells. 2011;11(2):165-171.
doi:10.1002/fuce.200900104 .

Žunić, Milan, Chevallier, Laure, di Bartolomeo, Elisabetta, D'Epifanio, Alessandra, Licoccia, Silvia, Traversa, Enrico, "Anode Supported Protonic Solid Oxide Fuel Cells Fabricated Using Electrophoretic Deposition" in Fuel Cells, 11, no. 2 (2011):165-171,
https://doi.org/10.1002/fuce.200900104 . .

TY  - JOUR
AU  - Žunić, Milan
AU  - Chevallier, Laure
AU  - Radojković, Aleksandar
AU  - Branković, Goran
AU  - Branković, Zorica
AU  - di Bartolomeo, Elisabetta
PY  - 2011
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/466
AB  - Cermet anode substrates Ni-BaCe0 9Y0 1O3-delta (Ni-BCY10) with varied ratios between Ni and BCY10 were prepared BCY10 powders were prepared by the citrate-nitrate auto-combustion method and anode substrates were prepared by the method of evaporation and decomposition of solutions and suspensions Sintered anode substrates were reduced and their properties were examined before and after reduction as a function of the ratio between Ni and BCY10 Microstructural properties of the pellets were investigated using X-ray diffraction analysis and field emission scanning electron microscopy The influence of the Ni BCY10 ratio on the microstructure of conducting paths through ceramic and metal parts was discussed Impedance spectroscopy measurements were used for evaluation of electrical properties of the anode pellets The high conductivity values of reduced anodes confirmed percolation through Ni particles even for an anode with a reduced amount of nickel Fuel cell tests were carried out in order to examine the influence of the Ni BCY10 ratio on fuel cell performance and to compare characteristics of cermet anodes with platinum electrodes The ratio between Ni and BCY10 did have a slight influence on the power output of fuel cells Fuel cells with a cermet anode demonstrated a higher power output compared to fuel cells with a platinum electrode
PB  - Elsevier Science Sa, Lausanne
T2  - Journal of Alloys and Compounds
T1  - Influence of the ratio between Ni and BaCe0 9Y0 1O3-delta on microstructural and electrical properties of proton conducting Ni-BaCe0 Y-9(0) O-1(3-delta) anodes
EP  - 1162
IS  - 4
SP  - 1157
VL  - 509
DO  - 10.1016/j.jallcom.2010.09.144
ER  - 

@article{
author = "Žunić, Milan and Chevallier, Laure and Radojković, Aleksandar and Branković, Goran and Branković, Zorica and di Bartolomeo, Elisabetta",
year = "2011",
abstract = "Cermet anode substrates Ni-BaCe0 9Y0 1O3-delta (Ni-BCY10) with varied ratios between Ni and BCY10 were prepared BCY10 powders were prepared by the citrate-nitrate auto-combustion method and anode substrates were prepared by the method of evaporation and decomposition of solutions and suspensions Sintered anode substrates were reduced and their properties were examined before and after reduction as a function of the ratio between Ni and BCY10 Microstructural properties of the pellets were investigated using X-ray diffraction analysis and field emission scanning electron microscopy The influence of the Ni BCY10 ratio on the microstructure of conducting paths through ceramic and metal parts was discussed Impedance spectroscopy measurements were used for evaluation of electrical properties of the anode pellets The high conductivity values of reduced anodes confirmed percolation through Ni particles even for an anode with a reduced amount of nickel Fuel cell tests were carried out in order to examine the influence of the Ni BCY10 ratio on fuel cell performance and to compare characteristics of cermet anodes with platinum electrodes The ratio between Ni and BCY10 did have a slight influence on the power output of fuel cells Fuel cells with a cermet anode demonstrated a higher power output compared to fuel cells with a platinum electrode",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Journal of Alloys and Compounds",
title = "Influence of the ratio between Ni and BaCe0 9Y0 1O3-delta on microstructural and electrical properties of proton conducting Ni-BaCe0 Y-9(0) O-1(3-delta) anodes",
pages = "1162-1157",
number = "4",
volume = "509",
doi = "10.1016/j.jallcom.2010.09.144"
}

Žunić, M., Chevallier, L., Radojković, A., Branković, G., Branković, Z.,& di Bartolomeo, E.. (2011). Influence of the ratio between Ni and BaCe0 9Y0 1O3-delta on microstructural and electrical properties of proton conducting Ni-BaCe0 Y-9(0) O-1(3-delta) anodes. in Journal of Alloys and Compounds
Elsevier Science Sa, Lausanne., 509(4), 1157-1162.
https://doi.org/10.1016/j.jallcom.2010.09.144

Žunić M, Chevallier L, Radojković A, Branković G, Branković Z, di Bartolomeo E. Influence of the ratio between Ni and BaCe0 9Y0 1O3-delta on microstructural and electrical properties of proton conducting Ni-BaCe0 Y-9(0) O-1(3-delta) anodes. in Journal of Alloys and Compounds. 2011;509(4):1157-1162.
doi:10.1016/j.jallcom.2010.09.144 .

Žunić, Milan, Chevallier, Laure, Radojković, Aleksandar, Branković, Goran, Branković, Zorica, di Bartolomeo, Elisabetta, "Influence of the ratio between Ni and BaCe0 9Y0 1O3-delta on microstructural and electrical properties of proton conducting Ni-BaCe0 Y-9(0) O-1(3-delta) anodes" in Journal of Alloys and Compounds, 509, no. 4 (2011):1157-1162,
https://doi.org/10.1016/j.jallcom.2010.09.144 . .

TY  - JOUR
AU  - Chevallier, Laure
AU  - Žunić, Milan
AU  - Esposito, Vincenzo
AU  - di Bartolomeo, Elisabetta
AU  - Traversa, Enrico
PY  - 2009
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/362
AB  - Nano-sized BaCe0.9Y0.1O3 - delta (BCY10) protonic conductor powders were used to prepare Ni-BCY10 cermets for anode-supported intermediate temperature solid oxide fuel cells. A new wet-chemical route was developed starting from Ni nitrates as precursors for NiO. BCY10 powders were Suspended in a Ni nitrate aqueous Solution that was evaporated to allow NiO precipitation on the BCY grains, obtaining NiO-BCY10 cermets. To obtain the final Ni-BCY10 anodes, pellets were reduced in dry H-2 at 700 degrees C. The structural and microstructural properties of the pellets were investigated using X-ray diffraction analysis and field emission scanning electron microscopy. A homogeneous dispersion of perovskite and nickel phases was observed. The chemical stability of the anodes was evaluated under wet H-2 and CO2 atmosphere at 700 degrees C. The electrical properties of the Ni-BCY10 pellets were evaluated using electrochemical impedance spectroscopy measurements. The Ni-BCY10 cermet electrodes showed large electronic conductivity, demonstrating percolation through the Ni particles, and low area specific resistance at the BCY10 interface. These characteristics make the cermet suitable for application in BCY-based protonic fuel cells. The developed chemical route offers a simple and low-cost procedure to obtain promising high performance anodes.
PB  - Elsevier, Amsterdam
T2  - Solid State Ionics
T1  - A wet-chemical route for the preparation of Ni-BaCe0.9Y0.1O3-delta cermet anodes for IT-SOFCs
EP  - 720
IS  - 9-10
SP  - 715
VL  - 180
DO  - 10.1016/j.ssi.2009.03.005
ER  - 

@article{
author = "Chevallier, Laure and Žunić, Milan and Esposito, Vincenzo and di Bartolomeo, Elisabetta and Traversa, Enrico",
year = "2009",
abstract = "Nano-sized BaCe0.9Y0.1O3 - delta (BCY10) protonic conductor powders were used to prepare Ni-BCY10 cermets for anode-supported intermediate temperature solid oxide fuel cells. A new wet-chemical route was developed starting from Ni nitrates as precursors for NiO. BCY10 powders were Suspended in a Ni nitrate aqueous Solution that was evaporated to allow NiO precipitation on the BCY grains, obtaining NiO-BCY10 cermets. To obtain the final Ni-BCY10 anodes, pellets were reduced in dry H-2 at 700 degrees C. The structural and microstructural properties of the pellets were investigated using X-ray diffraction analysis and field emission scanning electron microscopy. A homogeneous dispersion of perovskite and nickel phases was observed. The chemical stability of the anodes was evaluated under wet H-2 and CO2 atmosphere at 700 degrees C. The electrical properties of the Ni-BCY10 pellets were evaluated using electrochemical impedance spectroscopy measurements. The Ni-BCY10 cermet electrodes showed large electronic conductivity, demonstrating percolation through the Ni particles, and low area specific resistance at the BCY10 interface. These characteristics make the cermet suitable for application in BCY-based protonic fuel cells. The developed chemical route offers a simple and low-cost procedure to obtain promising high performance anodes.",
publisher = "Elsevier, Amsterdam",
journal = "Solid State Ionics",
title = "A wet-chemical route for the preparation of Ni-BaCe0.9Y0.1O3-delta cermet anodes for IT-SOFCs",
pages = "720-715",
number = "9-10",
volume = "180",
doi = "10.1016/j.ssi.2009.03.005"
}

Chevallier, L., Žunić, M., Esposito, V., di Bartolomeo, E.,& Traversa, E.. (2009). A wet-chemical route for the preparation of Ni-BaCe0.9Y0.1O3-delta cermet anodes for IT-SOFCs. in Solid State Ionics
Elsevier, Amsterdam., 180(9-10), 715-720.
https://doi.org/10.1016/j.ssi.2009.03.005

Chevallier L, Žunić M, Esposito V, di Bartolomeo E, Traversa E. A wet-chemical route for the preparation of Ni-BaCe0.9Y0.1O3-delta cermet anodes for IT-SOFCs. in Solid State Ionics. 2009;180(9-10):715-720.
doi:10.1016/j.ssi.2009.03.005 .

Chevallier, Laure, Žunić, Milan, Esposito, Vincenzo, di Bartolomeo, Elisabetta, Traversa, Enrico, "A wet-chemical route for the preparation of Ni-BaCe0.9Y0.1O3-delta cermet anodes for IT-SOFCs" in Solid State Ionics, 180, no. 9-10 (2009):715-720,
https://doi.org/10.1016/j.ssi.2009.03.005 . .

TY  - JOUR
AU  - Žunić, Milan
AU  - Chevallier, Laure
AU  - Deganello, Francesca
AU  - D'Epifanio, Alessandra
AU  - Licoccia, Silvia
AU  - di Bartolomeo, Elisabetta
AU  - Traversa, Enrico
PY  - 2009
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/356
AB  - Proton conducting BaCe0.9Y0.1O3-x (BCY10) thick films are deposited on cermet anodes made of nickel-yttrium doped barium cerate using electrophoretic deposition (EPD) technique. BCY10 powders are prepared by the citrate-nitrate auto-combustion method and the cermet anodes are prepared by the evaporation and decomposition solution and suspension method. The EPD parameters are optimized and the deposition time is varied between I and 5 min to obtain films with different thicknesses. The anode substrates and electrolyte films are co-sintered at 1550 degrees C for 2 h to obtain a dense electrolyte film keeping a suitable porosity in the anode, with a single heating treatment. The samples are characterized by Held emission scanning electron microscopy (FE-SEM) and energy dispersion spectroscopy (EDS). A prototype fuel cell is prepared depositing a composite La0.8Sr0.2Co0.8 Fe0.2O3 (LSCF)-BaCe0.9Yb0.1O3-delta (10YbBC) cathode oil the co-sintered half cell. Fuel cell tests that are performed at 650 C oil the prototype single cells show a maximum power density of 174 mW cm(-2).
PB  - Elsevier, Amsterdam
T2  - Journal of Power Sources
T1  - Electrophoretic deposition of dense BaCe0.9Y0.1O3-x electrolyte thick-films on Ni-based anodes for intermediate temperature solid oxide fuel cells
EP  - 422
IS  - 2
SP  - 417
VL  - 190
DO  - 10.1016/j.jpowsour.2009.01.046
ER  - 

@article{
author = "Žunić, Milan and Chevallier, Laure and Deganello, Francesca and D'Epifanio, Alessandra and Licoccia, Silvia and di Bartolomeo, Elisabetta and Traversa, Enrico",
year = "2009",
abstract = "Proton conducting BaCe0.9Y0.1O3-x (BCY10) thick films are deposited on cermet anodes made of nickel-yttrium doped barium cerate using electrophoretic deposition (EPD) technique. BCY10 powders are prepared by the citrate-nitrate auto-combustion method and the cermet anodes are prepared by the evaporation and decomposition solution and suspension method. The EPD parameters are optimized and the deposition time is varied between I and 5 min to obtain films with different thicknesses. The anode substrates and electrolyte films are co-sintered at 1550 degrees C for 2 h to obtain a dense electrolyte film keeping a suitable porosity in the anode, with a single heating treatment. The samples are characterized by Held emission scanning electron microscopy (FE-SEM) and energy dispersion spectroscopy (EDS). A prototype fuel cell is prepared depositing a composite La0.8Sr0.2Co0.8 Fe0.2O3 (LSCF)-BaCe0.9Yb0.1O3-delta (10YbBC) cathode oil the co-sintered half cell. Fuel cell tests that are performed at 650 C oil the prototype single cells show a maximum power density of 174 mW cm(-2).",
publisher = "Elsevier, Amsterdam",
journal = "Journal of Power Sources",
title = "Electrophoretic deposition of dense BaCe0.9Y0.1O3-x electrolyte thick-films on Ni-based anodes for intermediate temperature solid oxide fuel cells",
pages = "422-417",
number = "2",
volume = "190",
doi = "10.1016/j.jpowsour.2009.01.046"
}

Žunić, M., Chevallier, L., Deganello, F., D'Epifanio, A., Licoccia, S., di Bartolomeo, E.,& Traversa, E.. (2009). Electrophoretic deposition of dense BaCe0.9Y0.1O3-x electrolyte thick-films on Ni-based anodes for intermediate temperature solid oxide fuel cells. in Journal of Power Sources
Elsevier, Amsterdam., 190(2), 417-422.
https://doi.org/10.1016/j.jpowsour.2009.01.046

Žunić M, Chevallier L, Deganello F, D'Epifanio A, Licoccia S, di Bartolomeo E, Traversa E. Electrophoretic deposition of dense BaCe0.9Y0.1O3-x electrolyte thick-films on Ni-based anodes for intermediate temperature solid oxide fuel cells. in Journal of Power Sources. 2009;190(2):417-422.
doi:10.1016/j.jpowsour.2009.01.046 .

Žunić, Milan, Chevallier, Laure, Deganello, Francesca, D'Epifanio, Alessandra, Licoccia, Silvia, di Bartolomeo, Elisabetta, Traversa, Enrico, "Electrophoretic deposition of dense BaCe0.9Y0.1O3-x electrolyte thick-films on Ni-based anodes for intermediate temperature solid oxide fuel cells" in Journal of Power Sources, 190, no. 2 (2009):417-422,
https://doi.org/10.1016/j.jpowsour.2009.01.046 . .

TY  - JOUR
AU  - di Bartolomeo, Elisabetta
AU  - Žunić, Milan
AU  - Chevallier, Laure
AU  - D'Epifanio, Alessandra
AU  - Licoccia, Silvia
AU  - Traversa, E.
PY  - 2009
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/317
AB  - Anode-supported proton conducting solid oxide fuel cells (SOFCs) were fabricated by using electrophoretic deposition (EPD) for the electrolyte film deposition. BaCe0.9Y0.1O3-δ (BCY10) thick films were deposited on NiO-BCY10 substrates. The influence of the EPD parameters on the microstructure and electrical properties of BCY10 thick films was investigated. The anode substrates and electrolyte deposits were co-sintered at 1550°C for 2 h to obtain a dense electrolyte thick film, while keeping a suitable porosity in the anode. Innovative composites with La 0.8Sr0.2 Co0.8Fe0.2O3 (LSCF)-BaCe0.9Yb0.1O3-δ (10YbBC) composition were used as cathode materials. Prototype SOFCs were prepared by depositing the composite cathode on the co-sintered half cells. Fuel cell tests and electrochemical impedance spectroscopy (EIS) measurements were performed in the 550-700°C temperature range. The maximum power density of 296 mW cm -2 was achieved at 700°C.
T2  - ECS Transactions
T1  - Fabrication of proton conducting solid oxide fuel cell by using electrophoretic deposition
EP  - 584
IS  - 2 PART 1
SP  - 577
VL  - 25
DO  - 10.1149/1.3205569
ER  - 

@article{
author = "di Bartolomeo, Elisabetta and Žunić, Milan and Chevallier, Laure and D'Epifanio, Alessandra and Licoccia, Silvia and Traversa, E.",
year = "2009",
abstract = "Anode-supported proton conducting solid oxide fuel cells (SOFCs) were fabricated by using electrophoretic deposition (EPD) for the electrolyte film deposition. BaCe0.9Y0.1O3-δ (BCY10) thick films were deposited on NiO-BCY10 substrates. The influence of the EPD parameters on the microstructure and electrical properties of BCY10 thick films was investigated. The anode substrates and electrolyte deposits were co-sintered at 1550°C for 2 h to obtain a dense electrolyte thick film, while keeping a suitable porosity in the anode. Innovative composites with La 0.8Sr0.2 Co0.8Fe0.2O3 (LSCF)-BaCe0.9Yb0.1O3-δ (10YbBC) composition were used as cathode materials. Prototype SOFCs were prepared by depositing the composite cathode on the co-sintered half cells. Fuel cell tests and electrochemical impedance spectroscopy (EIS) measurements were performed in the 550-700°C temperature range. The maximum power density of 296 mW cm -2 was achieved at 700°C.",
journal = "ECS Transactions",
title = "Fabrication of proton conducting solid oxide fuel cell by using electrophoretic deposition",
pages = "584-577",
number = "2 PART 1",
volume = "25",
doi = "10.1149/1.3205569"
}

di Bartolomeo, E., Žunić, M., Chevallier, L., D'Epifanio, A., Licoccia, S.,& Traversa, E.. (2009). Fabrication of proton conducting solid oxide fuel cell by using electrophoretic deposition. in ECS Transactions, 25(2 PART 1), 577-584.
https://doi.org/10.1149/1.3205569

di Bartolomeo E, Žunić M, Chevallier L, D'Epifanio A, Licoccia S, Traversa E. Fabrication of proton conducting solid oxide fuel cell by using electrophoretic deposition. in ECS Transactions. 2009;25(2 PART 1):577-584.
doi:10.1149/1.3205569 .

di Bartolomeo, Elisabetta, Žunić, Milan, Chevallier, Laure, D'Epifanio, Alessandra, Licoccia, Silvia, Traversa, E., "Fabrication of proton conducting solid oxide fuel cell by using electrophoretic deposition" in ECS Transactions, 25, no. 2 PART 1 (2009):577-584,
https://doi.org/10.1149/1.3205569 . .