Stojanović, Biljana

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  • Stojanović, Biljana (18)
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Author's Bibliography

Band-gap engineering of BiFeO3 based powders. Influence on photocatalytic properties

Ilić, Nikola; Bobić, Jelena; Vijatović Petrović, Mirjana; Džunuzović, Adis; Stojanović, Biljana

(Electroceramics XVII 2020, Darmstadt, 24-28 August 2020, Online Conference, 2020)

TY  - CONF
AU  - Ilić, Nikola
AU  - Bobić, Jelena
AU  - Vijatović Petrović, Mirjana
AU  - Džunuzović, Adis
AU  - Stojanović, Biljana
PY  - 2020
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/2509
AB  - Bismuth ferrite (BiFeO3) is studied a lot in recent years because of its specific structure and potential to act
as single phase multiferrioic well above the room temperature. Thanks to the optical band gap energy of 2.3-
2.8 eV BiFeO3 is also an interesting material for photocatalytic and solar energy applications. Sol-gel and solid
state methods were used to synthesize BiFeO3-based powders. Two main methods would be used to modify the
band gap. First one is incorporation into composite materials with contribution of phase boundaries formed
between different phases of bismuth-iron oxides or BiFeO3 and silica-based substrate powders. Second one is
modification of powders by milling them with organic compounds in order to get defects and oxygen vacancies.
Composition, structure and microstructure of such way obtained powders were conducted and their influence
on variations in band-gap energy studied. Visible and UV-Vis light photocatalytic activity of synthesized materials
for decomposition of methylene blue solutions was tested and optimal composition and preparation route
for this application proposed, as well as the present mechanisms of adsorption and photocatalytic reaction.
PB  - Electroceramics XVII 2020, Darmstadt, 24-28 August 2020, Online Conference
C3  - Electroceramics XVII 2020, Darmstadt, 24-28 August 2020, Online Conference
T1  - Band-gap engineering of BiFeO3 based powders. Influence on photocatalytic properties
UR  - https://hdl.handle.net/21.15107/rcub_rimsi_2509
ER  - 
@conference{
author = "Ilić, Nikola and Bobić, Jelena and Vijatović Petrović, Mirjana and Džunuzović, Adis and Stojanović, Biljana",
year = "2020",
abstract = "Bismuth ferrite (BiFeO3) is studied a lot in recent years because of its specific structure and potential to act
as single phase multiferrioic well above the room temperature. Thanks to the optical band gap energy of 2.3-
2.8 eV BiFeO3 is also an interesting material for photocatalytic and solar energy applications. Sol-gel and solid
state methods were used to synthesize BiFeO3-based powders. Two main methods would be used to modify the
band gap. First one is incorporation into composite materials with contribution of phase boundaries formed
between different phases of bismuth-iron oxides or BiFeO3 and silica-based substrate powders. Second one is
modification of powders by milling them with organic compounds in order to get defects and oxygen vacancies.
Composition, structure and microstructure of such way obtained powders were conducted and their influence
on variations in band-gap energy studied. Visible and UV-Vis light photocatalytic activity of synthesized materials
for decomposition of methylene blue solutions was tested and optimal composition and preparation route
for this application proposed, as well as the present mechanisms of adsorption and photocatalytic reaction.",
publisher = "Electroceramics XVII 2020, Darmstadt, 24-28 August 2020, Online Conference",
journal = "Electroceramics XVII 2020, Darmstadt, 24-28 August 2020, Online Conference",
title = "Band-gap engineering of BiFeO3 based powders. Influence on photocatalytic properties",
url = "https://hdl.handle.net/21.15107/rcub_rimsi_2509"
}
Ilić, N., Bobić, J., Vijatović Petrović, M., Džunuzović, A.,& Stojanović, B.. (2020). Band-gap engineering of BiFeO3 based powders. Influence on photocatalytic properties. in Electroceramics XVII 2020, Darmstadt, 24-28 August 2020, Online Conference
Electroceramics XVII 2020, Darmstadt, 24-28 August 2020, Online Conference..
https://hdl.handle.net/21.15107/rcub_rimsi_2509
Ilić N, Bobić J, Vijatović Petrović M, Džunuzović A, Stojanović B. Band-gap engineering of BiFeO3 based powders. Influence on photocatalytic properties. in Electroceramics XVII 2020, Darmstadt, 24-28 August 2020, Online Conference. 2020;.
https://hdl.handle.net/21.15107/rcub_rimsi_2509 .
Ilić, Nikola, Bobić, Jelena, Vijatović Petrović, Mirjana, Džunuzović, Adis, Stojanović, Biljana, "Band-gap engineering of BiFeO3 based powders. Influence on photocatalytic properties" in Electroceramics XVII 2020, Darmstadt, 24-28 August 2020, Online Conference (2020),
https://hdl.handle.net/21.15107/rcub_rimsi_2509 .

INFLUENCE OF FERRITES PHASE ON PROPERTIES OF THE BARIUM ZIRCONIUM TITANATE BASED MULTIFERROIC COMPOSITES

Džunuzović, Adis; Vijatović Petrović, Mirjana; Bobić, Jelena; Ilić, Nikola; Stojanović, Biljana

(Faculty of Technology, University of Novi Sad Bul. cara Lazara 1, 21000 Novi Sad, Serbia, 2019)

TY  - CONF
AU  - Džunuzović, Adis
AU  - Vijatović Petrović, Mirjana
AU  - Bobić, Jelena
AU  - Ilić, Nikola
AU  - Stojanović, Biljana
PY  - 2019
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/2600
AB  - Multiferroic composites with general formula Ba(Ti0.95Zr0.05)O3–Ni0.7Zn0.3Fe2O4/
CoFe2O4/Ni0.7Cu0.01Sm0.05Zn0.29Fe1.95O4, (BTZr(95-5)–NZF/CF/NCuSmZF) were
prepared by mixing chemically obtained different types of ferrites and BTZ(95-5)
powders in the planetary mill for 24 h. The optimization of sintering process was
performed and powders were pressed and sintered at 1300 °C for obtained composites
samples. From X-ray analysis for single phase and composites ceramics can be noticed
the formation of crystallized structure of ferrites and barium zirconium titanate. SEM analyses indicated the formation of two types nanosized grains, polygonal ferromagnetic
and rounded ferroelectric grains.
The electrical properties of these materials were investigated using impedance
spectroscopy and analysis of ferroelectric measurements. Impedance analysis of all
investigated samples has shown different relaxation processes that originated from the
grain and grain boundary contributions. The results of polarization vs. electric field
measurements have shown the influence of magnetic phase type and its concentration on
the ferroelectric properties of the composites. Due to high conductivity of ferrite phases
and presence of interfacial polarization, the shapes of these curves differed from the
conventional ferroelectric materials.
PB  - Faculty of Technology, University of Novi Sad Bul. cara Lazara 1, 21000 Novi Sad, Serbia
C3  - 13th Conference for Young Scientists in Ceramics, CYSC-2019, Novi Sad, Serbia
T1  - INFLUENCE OF FERRITES PHASE ON PROPERTIES OF THE BARIUM ZIRCONIUM TITANATE BASED MULTIFERROIC COMPOSITES
UR  - https://hdl.handle.net/21.15107/rcub_rimsi_2600
ER  - 
@conference{
author = "Džunuzović, Adis and Vijatović Petrović, Mirjana and Bobić, Jelena and Ilić, Nikola and Stojanović, Biljana",
year = "2019",
abstract = "Multiferroic composites with general formula Ba(Ti0.95Zr0.05)O3–Ni0.7Zn0.3Fe2O4/
CoFe2O4/Ni0.7Cu0.01Sm0.05Zn0.29Fe1.95O4, (BTZr(95-5)–NZF/CF/NCuSmZF) were
prepared by mixing chemically obtained different types of ferrites and BTZ(95-5)
powders in the planetary mill for 24 h. The optimization of sintering process was
performed and powders were pressed and sintered at 1300 °C for obtained composites
samples. From X-ray analysis for single phase and composites ceramics can be noticed
the formation of crystallized structure of ferrites and barium zirconium titanate. SEM analyses indicated the formation of two types nanosized grains, polygonal ferromagnetic
and rounded ferroelectric grains.
The electrical properties of these materials were investigated using impedance
spectroscopy and analysis of ferroelectric measurements. Impedance analysis of all
investigated samples has shown different relaxation processes that originated from the
grain and grain boundary contributions. The results of polarization vs. electric field
measurements have shown the influence of magnetic phase type and its concentration on
the ferroelectric properties of the composites. Due to high conductivity of ferrite phases
and presence of interfacial polarization, the shapes of these curves differed from the
conventional ferroelectric materials.",
publisher = "Faculty of Technology, University of Novi Sad Bul. cara Lazara 1, 21000 Novi Sad, Serbia",
journal = "13th Conference for Young Scientists in Ceramics, CYSC-2019, Novi Sad, Serbia",
title = "INFLUENCE OF FERRITES PHASE ON PROPERTIES OF THE BARIUM ZIRCONIUM TITANATE BASED MULTIFERROIC COMPOSITES",
url = "https://hdl.handle.net/21.15107/rcub_rimsi_2600"
}
Džunuzović, A., Vijatović Petrović, M., Bobić, J., Ilić, N.,& Stojanović, B.. (2019). INFLUENCE OF FERRITES PHASE ON PROPERTIES OF THE BARIUM ZIRCONIUM TITANATE BASED MULTIFERROIC COMPOSITES. in 13th Conference for Young Scientists in Ceramics, CYSC-2019, Novi Sad, Serbia
Faculty of Technology, University of Novi Sad Bul. cara Lazara 1, 21000 Novi Sad, Serbia..
https://hdl.handle.net/21.15107/rcub_rimsi_2600
Džunuzović A, Vijatović Petrović M, Bobić J, Ilić N, Stojanović B. INFLUENCE OF FERRITES PHASE ON PROPERTIES OF THE BARIUM ZIRCONIUM TITANATE BASED MULTIFERROIC COMPOSITES. in 13th Conference for Young Scientists in Ceramics, CYSC-2019, Novi Sad, Serbia. 2019;.
https://hdl.handle.net/21.15107/rcub_rimsi_2600 .
Džunuzović, Adis, Vijatović Petrović, Mirjana, Bobić, Jelena, Ilić, Nikola, Stojanović, Biljana, "INFLUENCE OF FERRITES PHASE ON PROPERTIES OF THE BARIUM ZIRCONIUM TITANATE BASED MULTIFERROIC COMPOSITES" in 13th Conference for Young Scientists in Ceramics, CYSC-2019, Novi Sad, Serbia (2019),
https://hdl.handle.net/21.15107/rcub_rimsi_2600 .

Sintering heating and cooling rates as a method of modifying electrical properties of BiFeO3 ceramics

Ilić, Nikola; Bobić, Jelena; Vijatović Petrović, Mirjana; Džunuzović, Adis; Stojanović, Biljana

(Materials Research Society of Serbia Knez Mihailova 35/IV, P.O.Box 433, 11000 Belgrade, Serbia http://www.mrs‐serbia.org.rs, 2019)

TY  - CONF
AU  - Ilić, Nikola
AU  - Bobić, Jelena
AU  - Vijatović Petrović, Mirjana
AU  - Džunuzović, Adis
AU  - Stojanović, Biljana
PY  - 2019
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/2616
AB  - Bismut ferrite powder was prepared by sol-gel method. It was calcined at 600 °C and then milled
in order to break agglomerates and eventually obtain ceramic samples of high density. Such way
treated powders were pressed uniaxially under 196 MPa and sintered at 800 °C. Conventionaly
sintered samples were heated by the rate of 10 °C/min and furnace cooled. Other samples were
inserted into preheated oven and/or taken out from the hot oven directly to air or water at room
temperature. Influence of heating and cooling rates on structure, microstructure and electrical
properties were studied. Reducing the processing time in temperature interval between 447 °C and
767 °C prevents formation of secondary phases, but the effect on phase composition is not large. It
is significantly easier to notice the effect on electrical properties.
PB  - Materials Research Society of Serbia Knez Mihailova 35/IV, P.O.Box 433, 11000 Belgrade, Serbia http://www.mrs‐serbia.org.rs
C3  - Twenty-first YUCOMAT 2019 & Eleventh WRTCS 2019 Herceg Novi, September 2 - 6, 2019
T1  - Sintering heating and cooling rates as a method of modifying electrical properties of BiFeO3 ceramics
UR  - https://hdl.handle.net/21.15107/rcub_rimsi_2616
ER  - 
@conference{
author = "Ilić, Nikola and Bobić, Jelena and Vijatović Petrović, Mirjana and Džunuzović, Adis and Stojanović, Biljana",
year = "2019",
abstract = "Bismut ferrite powder was prepared by sol-gel method. It was calcined at 600 °C and then milled
in order to break agglomerates and eventually obtain ceramic samples of high density. Such way
treated powders were pressed uniaxially under 196 MPa and sintered at 800 °C. Conventionaly
sintered samples were heated by the rate of 10 °C/min and furnace cooled. Other samples were
inserted into preheated oven and/or taken out from the hot oven directly to air or water at room
temperature. Influence of heating and cooling rates on structure, microstructure and electrical
properties were studied. Reducing the processing time in temperature interval between 447 °C and
767 °C prevents formation of secondary phases, but the effect on phase composition is not large. It
is significantly easier to notice the effect on electrical properties.",
publisher = "Materials Research Society of Serbia Knez Mihailova 35/IV, P.O.Box 433, 11000 Belgrade, Serbia http://www.mrs‐serbia.org.rs",
journal = "Twenty-first YUCOMAT 2019 & Eleventh WRTCS 2019 Herceg Novi, September 2 - 6, 2019",
title = "Sintering heating and cooling rates as a method of modifying electrical properties of BiFeO3 ceramics",
url = "https://hdl.handle.net/21.15107/rcub_rimsi_2616"
}
Ilić, N., Bobić, J., Vijatović Petrović, M., Džunuzović, A.,& Stojanović, B.. (2019). Sintering heating and cooling rates as a method of modifying electrical properties of BiFeO3 ceramics. in Twenty-first YUCOMAT 2019 & Eleventh WRTCS 2019 Herceg Novi, September 2 - 6, 2019
Materials Research Society of Serbia Knez Mihailova 35/IV, P.O.Box 433, 11000 Belgrade, Serbia http://www.mrs‐serbia.org.rs..
https://hdl.handle.net/21.15107/rcub_rimsi_2616
Ilić N, Bobić J, Vijatović Petrović M, Džunuzović A, Stojanović B. Sintering heating and cooling rates as a method of modifying electrical properties of BiFeO3 ceramics. in Twenty-first YUCOMAT 2019 & Eleventh WRTCS 2019 Herceg Novi, September 2 - 6, 2019. 2019;.
https://hdl.handle.net/21.15107/rcub_rimsi_2616 .
Ilić, Nikola, Bobić, Jelena, Vijatović Petrović, Mirjana, Džunuzović, Adis, Stojanović, Biljana, "Sintering heating and cooling rates as a method of modifying electrical properties of BiFeO3 ceramics" in Twenty-first YUCOMAT 2019 & Eleventh WRTCS 2019 Herceg Novi, September 2 - 6, 2019 (2019),
https://hdl.handle.net/21.15107/rcub_rimsi_2616 .

PHOTOCATALYTIC ACTIVITY OF BiFeO3-BASED POWDERS

Ilić, Nikola; Bobić, Jelena; Vijatović Petrović, Mirjana; Džunuzović, Adis; Stojanović, Biljana

(Institute for Multidisciplinary Research, University of Belgrade Kneza Višeslava 1, 11000 Belgrade, Serbia, 2019)

TY  - CONF
AU  - Ilić, Nikola
AU  - Bobić, Jelena
AU  - Vijatović Petrović, Mirjana
AU  - Džunuzović, Adis
AU  - Stojanović, Biljana
PY  - 2019
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/2487
AB  - Bismuth-ferrite (BiFeO3) is studied a lot in recent years due to its specific
multiferroic properties. Thanks to the optical bandgap energy of 2.3-2.8 eV [1],
BiFeO3-based materials are also interesting for photocatalytic and solar energy
applications. Sol-gel methods were used to produce BiFeO3 and BiFeO3-modified diatomaceous earth. These powders were characterized, and their visible light
photocatalytic activity for decomposition of some organic dyes was tested in acidic,
close-to-neutral and alkaline conditions. Fenton-like catalysis was also tested for
those materials. Influence of synthesis method, microstructure, ageing and
composition on dye degradation helped in proposing the mechanism of adsorption
and photocatalytic processes.
PB  - Institute for Multidisciplinary Research, University of Belgrade Kneza Višeslava 1, 11000 Belgrade, Serbia
C3  - 5th Conference of The Serbian Society for Ceramic Materials
T1  - PHOTOCATALYTIC ACTIVITY OF BiFeO3-BASED POWDERS
UR  - https://hdl.handle.net/21.15107/rcub_rimsi_2487
ER  - 
@conference{
author = "Ilić, Nikola and Bobić, Jelena and Vijatović Petrović, Mirjana and Džunuzović, Adis and Stojanović, Biljana",
year = "2019",
abstract = "Bismuth-ferrite (BiFeO3) is studied a lot in recent years due to its specific
multiferroic properties. Thanks to the optical bandgap energy of 2.3-2.8 eV [1],
BiFeO3-based materials are also interesting for photocatalytic and solar energy
applications. Sol-gel methods were used to produce BiFeO3 and BiFeO3-modified diatomaceous earth. These powders were characterized, and their visible light
photocatalytic activity for decomposition of some organic dyes was tested in acidic,
close-to-neutral and alkaline conditions. Fenton-like catalysis was also tested for
those materials. Influence of synthesis method, microstructure, ageing and
composition on dye degradation helped in proposing the mechanism of adsorption
and photocatalytic processes.",
publisher = "Institute for Multidisciplinary Research, University of Belgrade Kneza Višeslava 1, 11000 Belgrade, Serbia",
journal = "5th Conference of The Serbian Society for Ceramic Materials",
title = "PHOTOCATALYTIC ACTIVITY OF BiFeO3-BASED POWDERS",
url = "https://hdl.handle.net/21.15107/rcub_rimsi_2487"
}
Ilić, N., Bobić, J., Vijatović Petrović, M., Džunuzović, A.,& Stojanović, B.. (2019). PHOTOCATALYTIC ACTIVITY OF BiFeO3-BASED POWDERS. in 5th Conference of The Serbian Society for Ceramic Materials
Institute for Multidisciplinary Research, University of Belgrade Kneza Višeslava 1, 11000 Belgrade, Serbia..
https://hdl.handle.net/21.15107/rcub_rimsi_2487
Ilić N, Bobić J, Vijatović Petrović M, Džunuzović A, Stojanović B. PHOTOCATALYTIC ACTIVITY OF BiFeO3-BASED POWDERS. in 5th Conference of The Serbian Society for Ceramic Materials. 2019;.
https://hdl.handle.net/21.15107/rcub_rimsi_2487 .
Ilić, Nikola, Bobić, Jelena, Vijatović Petrović, Mirjana, Džunuzović, Adis, Stojanović, Biljana, "PHOTOCATALYTIC ACTIVITY OF BiFeO3-BASED POWDERS" in 5th Conference of The Serbian Society for Ceramic Materials (2019),
https://hdl.handle.net/21.15107/rcub_rimsi_2487 .

PROPERTIES OF PbZr0.52Ti0.48O3 - NiZnFe2O4, CoFe2O4 MULTIFERROIC COMPOSITES OBTAINED BY AUTO-COMBUSTION SYNTHESIS

Džunuzović, Adis; Bobić, Jelena; Vijatović Petrović, Mirjana; Ilić, Nikola; Ivanov, Maxim; Makovec, Darko; Stojanović, Biljana

(Faculty of Technology, University of Novi Sad Bul. cara Lazara 1, 21000 Novi Sad, Serbia, 2017)

TY  - CONF
AU  - Džunuzović, Adis
AU  - Bobić, Jelena
AU  - Vijatović Petrović, Mirjana
AU  - Ilić, Nikola
AU  - Ivanov, Maxim
AU  - Makovec, Darko
AU  - Stojanović, Biljana
PY  - 2017
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/2597
AB  - Nickel zinc ferrite (NZF), cobalt ferrite (CF) and barium titanate (BT) nanosized powders were synthesised by auto-combustion method. Multiferroic composites with the formula xPbZr0.52Ti0.48O3+(1-x)CoFe2O4 and xPbZr0.52Ti0.48O3+(1-x)Ni0.7Zn0.3Fe2O4 (x=0.8 and 0.9) were prepared from nickel zinc ferrite, cobalt ferrite and barium titanate powders by mixing in planetary ball mill for 24 h. Pellets were sintered at different temperatures in order to obtain dense, two phased composites. XRD data indicated the formation of well crystallized structure of PZT and NZF/CF phase in the composite ceramics. SEM micrographs revealed a uniform grain distribution of both phases without any secondary phases.
Magnetic measurements of all sintered composites were carried out and presented in Figure 1. All the composite samples exhibit typical ferromagnetic hysteresis loop, indicating the presence of the order magnetic structure. Saturation magnetization moment decreases with increasing PZT content, because of non-magnetic PZT phase
PB  - Faculty of Technology, University of Novi Sad Bul. cara Lazara 1, 21000 Novi Sad, Serbia
C3  - 12th Conference for young scientists in ceramics, October 18-21, 2017, Novi Sad
T1  - PROPERTIES OF PbZr0.52Ti0.48O3 - NiZnFe2O4, CoFe2O4 MULTIFERROIC COMPOSITES OBTAINED BY AUTO-COMBUSTION SYNTHESIS
UR  - https://hdl.handle.net/21.15107/rcub_rimsi_2597
ER  - 
@conference{
author = "Džunuzović, Adis and Bobić, Jelena and Vijatović Petrović, Mirjana and Ilić, Nikola and Ivanov, Maxim and Makovec, Darko and Stojanović, Biljana",
year = "2017",
abstract = "Nickel zinc ferrite (NZF), cobalt ferrite (CF) and barium titanate (BT) nanosized powders were synthesised by auto-combustion method. Multiferroic composites with the formula xPbZr0.52Ti0.48O3+(1-x)CoFe2O4 and xPbZr0.52Ti0.48O3+(1-x)Ni0.7Zn0.3Fe2O4 (x=0.8 and 0.9) were prepared from nickel zinc ferrite, cobalt ferrite and barium titanate powders by mixing in planetary ball mill for 24 h. Pellets were sintered at different temperatures in order to obtain dense, two phased composites. XRD data indicated the formation of well crystallized structure of PZT and NZF/CF phase in the composite ceramics. SEM micrographs revealed a uniform grain distribution of both phases without any secondary phases.
Magnetic measurements of all sintered composites were carried out and presented in Figure 1. All the composite samples exhibit typical ferromagnetic hysteresis loop, indicating the presence of the order magnetic structure. Saturation magnetization moment decreases with increasing PZT content, because of non-magnetic PZT phase",
publisher = "Faculty of Technology, University of Novi Sad Bul. cara Lazara 1, 21000 Novi Sad, Serbia",
journal = "12th Conference for young scientists in ceramics, October 18-21, 2017, Novi Sad",
title = "PROPERTIES OF PbZr0.52Ti0.48O3 - NiZnFe2O4, CoFe2O4 MULTIFERROIC COMPOSITES OBTAINED BY AUTO-COMBUSTION SYNTHESIS",
url = "https://hdl.handle.net/21.15107/rcub_rimsi_2597"
}
Džunuzović, A., Bobić, J., Vijatović Petrović, M., Ilić, N., Ivanov, M., Makovec, D.,& Stojanović, B.. (2017). PROPERTIES OF PbZr0.52Ti0.48O3 - NiZnFe2O4, CoFe2O4 MULTIFERROIC COMPOSITES OBTAINED BY AUTO-COMBUSTION SYNTHESIS. in 12th Conference for young scientists in ceramics, October 18-21, 2017, Novi Sad
Faculty of Technology, University of Novi Sad Bul. cara Lazara 1, 21000 Novi Sad, Serbia..
https://hdl.handle.net/21.15107/rcub_rimsi_2597
Džunuzović A, Bobić J, Vijatović Petrović M, Ilić N, Ivanov M, Makovec D, Stojanović B. PROPERTIES OF PbZr0.52Ti0.48O3 - NiZnFe2O4, CoFe2O4 MULTIFERROIC COMPOSITES OBTAINED BY AUTO-COMBUSTION SYNTHESIS. in 12th Conference for young scientists in ceramics, October 18-21, 2017, Novi Sad. 2017;.
https://hdl.handle.net/21.15107/rcub_rimsi_2597 .
Džunuzović, Adis, Bobić, Jelena, Vijatović Petrović, Mirjana, Ilić, Nikola, Ivanov, Maxim, Makovec, Darko, Stojanović, Biljana, "PROPERTIES OF PbZr0.52Ti0.48O3 - NiZnFe2O4, CoFe2O4 MULTIFERROIC COMPOSITES OBTAINED BY AUTO-COMBUSTION SYNTHESIS" in 12th Conference for young scientists in ceramics, October 18-21, 2017, Novi Sad (2017),
https://hdl.handle.net/21.15107/rcub_rimsi_2597 .

CORRELATION BETWEEN STRUCTURE AND ELECTRICAL CHARACTERISTICS IN SAMARIUM DOPED BARIUM TITANATE SYSTEMS

Vijatović Petrović, Mirjana; Grigalaitis, Robertas; Džunuzović, Adis; Bobić, Jelena; Ilić, Nikola; Stojanović, Biljana

(Institute for Multidisciplinary Research, University of Belgrade Kneza Višeslava 1, 11000 Belgrade, Serbia, 2017)

TY  - CONF
AU  - Vijatović Petrović, Mirjana
AU  - Grigalaitis, Robertas
AU  - Džunuzović, Adis
AU  - Bobić, Jelena
AU  - Ilić, Nikola
AU  - Stojanović, Biljana
PY  - 2017
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/2555
AB  - Conventional solid-state method was used to prepare powders of barium titanate (BT) doped with different concentration of Sm. Influence of Sm addition on the structure modification, grain growth inhibition and microstructure development was studied. Dielectric properties of doped samples were significantly modified. With doping, a diffuse kind of ferro-para phase transition was induced, phase transition positions were moved and dielectric permittivity values were lowered. On the other hand, Sm doping affected the decrease of dielectric losses. The impedance complex plane plots showed a one single semicircular arc, indicating grain contribution as a main effect on the total conduction of the doped materials. On the other hand, different electro-active regions in the modulus plane plots were distinguish. The comparison between impedance and modulus scaling behavior presented the localized movement of charge carriers. P-E hysteresis loops have shown the dilution of ferroelectric properties with Sm doping.
PB  - Institute for Multidisciplinary Research, University of Belgrade Kneza Višeslava 1, 11000 Belgrade, Serbia
C3  - 4th Conference of The Serbian Society for Ceramic Materials
T1  - CORRELATION BETWEEN STRUCTURE AND ELECTRICAL CHARACTERISTICS IN SAMARIUM DOPED BARIUM TITANATE SYSTEMS
UR  - https://hdl.handle.net/21.15107/rcub_rimsi_2555
ER  - 
@conference{
author = "Vijatović Petrović, Mirjana and Grigalaitis, Robertas and Džunuzović, Adis and Bobić, Jelena and Ilić, Nikola and Stojanović, Biljana",
year = "2017",
abstract = "Conventional solid-state method was used to prepare powders of barium titanate (BT) doped with different concentration of Sm. Influence of Sm addition on the structure modification, grain growth inhibition and microstructure development was studied. Dielectric properties of doped samples were significantly modified. With doping, a diffuse kind of ferro-para phase transition was induced, phase transition positions were moved and dielectric permittivity values were lowered. On the other hand, Sm doping affected the decrease of dielectric losses. The impedance complex plane plots showed a one single semicircular arc, indicating grain contribution as a main effect on the total conduction of the doped materials. On the other hand, different electro-active regions in the modulus plane plots were distinguish. The comparison between impedance and modulus scaling behavior presented the localized movement of charge carriers. P-E hysteresis loops have shown the dilution of ferroelectric properties with Sm doping.",
publisher = "Institute for Multidisciplinary Research, University of Belgrade Kneza Višeslava 1, 11000 Belgrade, Serbia",
journal = "4th Conference of The Serbian Society for Ceramic Materials",
title = "CORRELATION BETWEEN STRUCTURE AND ELECTRICAL CHARACTERISTICS IN SAMARIUM DOPED BARIUM TITANATE SYSTEMS",
url = "https://hdl.handle.net/21.15107/rcub_rimsi_2555"
}
Vijatović Petrović, M., Grigalaitis, R., Džunuzović, A., Bobić, J., Ilić, N.,& Stojanović, B.. (2017). CORRELATION BETWEEN STRUCTURE AND ELECTRICAL CHARACTERISTICS IN SAMARIUM DOPED BARIUM TITANATE SYSTEMS. in 4th Conference of The Serbian Society for Ceramic Materials
Institute for Multidisciplinary Research, University of Belgrade Kneza Višeslava 1, 11000 Belgrade, Serbia..
https://hdl.handle.net/21.15107/rcub_rimsi_2555
Vijatović Petrović M, Grigalaitis R, Džunuzović A, Bobić J, Ilić N, Stojanović B. CORRELATION BETWEEN STRUCTURE AND ELECTRICAL CHARACTERISTICS IN SAMARIUM DOPED BARIUM TITANATE SYSTEMS. in 4th Conference of The Serbian Society for Ceramic Materials. 2017;.
https://hdl.handle.net/21.15107/rcub_rimsi_2555 .
Vijatović Petrović, Mirjana, Grigalaitis, Robertas, Džunuzović, Adis, Bobić, Jelena, Ilić, Nikola, Stojanović, Biljana, "CORRELATION BETWEEN STRUCTURE AND ELECTRICAL CHARACTERISTICS IN SAMARIUM DOPED BARIUM TITANATE SYSTEMS" in 4th Conference of The Serbian Society for Ceramic Materials (2017),
https://hdl.handle.net/21.15107/rcub_rimsi_2555 .

THE OVERVIEW OF BARIUM TITANATE PROPERTIES AND APPLICATION OPPORTUNITIES

Vijatović Petrović, Mirjana; Džunuzović, Adis; Bobić, Jelena; Grigalaitis, Robertas; Stojanović, Biljana

(Institute for Multidisciplinary Research, University of Belgrade Kneza Višeslava 1, 11000 Belgrade, Serbia, 2017)

TY  - CONF
AU  - Vijatović Petrović, Mirjana
AU  - Džunuzović, Adis
AU  - Bobić, Jelena
AU  - Grigalaitis, Robertas
AU  - Stojanović, Biljana
PY  - 2017
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/2557
AB  - Barium titanate (BT) is a ferroelectric material with a perovskite structure important in the field of electronics. Due to high flexiblity of its crystal lattice it has the capabilty to host ions with different oxidation state and careful selection of dopants could enable tailoring of barium titanate structure and electrical properties.
Barium titanate doped with La, Sb, Sm, Nb and Mn will be presented in the light of structural changes and their influence on electrical properties modification. Doping with La, Sb and Sm in very low concentrations induces symmetry change from tatragonal to pseudo-cubic. La, Sb, Nb and Sm are proven to be grain growth inhibitors, with the different effect on obtained ceramics density. Dielectric permittivity value was significantly changed depending on dopant kind and concentration. Partial substitution of Ba or Ti ions by some of this dopants induced the movement of phase transition peaks to the lower temperatures and caused the formation of diffuse phase transition. In this way, the application of barium titanate can be widened from capacitors to PTCR sensors, gas and humidity sensors, etc.
In the recent years, there is a growing interest for multiferroic materials with barium titanate as a main component. When being mixed with ferrites in the multiferroic composites the electrical properties of barium titanate are being compromised. Dielectric permittivity starts to decrease in comparison with pure BT ferroelectric material. Using of doped barium titanate as a part of the multiferroic material could enhance the overall dielectric permittivity of barium titanate and therefore the dielectric properties of the multiferroic material. Mixing route was used for the preparation of BaTiO3-NiFe2O4, BaTiO3-NiZnFe2O4, Ba(Sb)TiO3- NiFe2O4 composite materials. Magnetic and electrical properties of multiferroic materials have shown the dilution effect due to existence of both, ferroelectric and ferrite phases in the samematerial.
PB  - Institute for Multidisciplinary Research, University of Belgrade Kneza Višeslava 1, 11000 Belgrade, Serbia
C3  - 4th Conference of The Serbian Society for Ceramic Materials
T1  - THE OVERVIEW OF BARIUM TITANATE PROPERTIES AND APPLICATION OPPORTUNITIES
UR  - https://hdl.handle.net/21.15107/rcub_rimsi_2557
ER  - 
@conference{
author = "Vijatović Petrović, Mirjana and Džunuzović, Adis and Bobić, Jelena and Grigalaitis, Robertas and Stojanović, Biljana",
year = "2017",
abstract = "Barium titanate (BT) is a ferroelectric material with a perovskite structure important in the field of electronics. Due to high flexiblity of its crystal lattice it has the capabilty to host ions with different oxidation state and careful selection of dopants could enable tailoring of barium titanate structure and electrical properties.
Barium titanate doped with La, Sb, Sm, Nb and Mn will be presented in the light of structural changes and their influence on electrical properties modification. Doping with La, Sb and Sm in very low concentrations induces symmetry change from tatragonal to pseudo-cubic. La, Sb, Nb and Sm are proven to be grain growth inhibitors, with the different effect on obtained ceramics density. Dielectric permittivity value was significantly changed depending on dopant kind and concentration. Partial substitution of Ba or Ti ions by some of this dopants induced the movement of phase transition peaks to the lower temperatures and caused the formation of diffuse phase transition. In this way, the application of barium titanate can be widened from capacitors to PTCR sensors, gas and humidity sensors, etc.
In the recent years, there is a growing interest for multiferroic materials with barium titanate as a main component. When being mixed with ferrites in the multiferroic composites the electrical properties of barium titanate are being compromised. Dielectric permittivity starts to decrease in comparison with pure BT ferroelectric material. Using of doped barium titanate as a part of the multiferroic material could enhance the overall dielectric permittivity of barium titanate and therefore the dielectric properties of the multiferroic material. Mixing route was used for the preparation of BaTiO3-NiFe2O4, BaTiO3-NiZnFe2O4, Ba(Sb)TiO3- NiFe2O4 composite materials. Magnetic and electrical properties of multiferroic materials have shown the dilution effect due to existence of both, ferroelectric and ferrite phases in the samematerial.",
publisher = "Institute for Multidisciplinary Research, University of Belgrade Kneza Višeslava 1, 11000 Belgrade, Serbia",
journal = "4th Conference of The Serbian Society for Ceramic Materials",
title = "THE OVERVIEW OF BARIUM TITANATE PROPERTIES AND APPLICATION OPPORTUNITIES",
url = "https://hdl.handle.net/21.15107/rcub_rimsi_2557"
}
Vijatović Petrović, M., Džunuzović, A., Bobić, J., Grigalaitis, R.,& Stojanović, B.. (2017). THE OVERVIEW OF BARIUM TITANATE PROPERTIES AND APPLICATION OPPORTUNITIES. in 4th Conference of The Serbian Society for Ceramic Materials
Institute for Multidisciplinary Research, University of Belgrade Kneza Višeslava 1, 11000 Belgrade, Serbia..
https://hdl.handle.net/21.15107/rcub_rimsi_2557
Vijatović Petrović M, Džunuzović A, Bobić J, Grigalaitis R, Stojanović B. THE OVERVIEW OF BARIUM TITANATE PROPERTIES AND APPLICATION OPPORTUNITIES. in 4th Conference of The Serbian Society for Ceramic Materials. 2017;.
https://hdl.handle.net/21.15107/rcub_rimsi_2557 .
Vijatović Petrović, Mirjana, Džunuzović, Adis, Bobić, Jelena, Grigalaitis, Robertas, Stojanović, Biljana, "THE OVERVIEW OF BARIUM TITANATE PROPERTIES AND APPLICATION OPPORTUNITIES" in 4th Conference of The Serbian Society for Ceramic Materials (2017),
https://hdl.handle.net/21.15107/rcub_rimsi_2557 .

BiFeO3 CERAMICS DENSIFICATION STUDY

Ilić, Nikola; Bobić, Jelena; Džunuzović, Adis; Makarović, Maja; Rojac, Tadej; Stojanović, Biljana

(Faculty of Technology, University of Novi Sad Bul. cara Lazara 1, 21000 Novi Sad, Serbia, 2015)

TY  - CONF
AU  - Ilić, Nikola
AU  - Bobić, Jelena
AU  - Džunuzović, Adis
AU  - Makarović, Maja
AU  - Rojac, Tadej
AU  - Stojanović, Biljana
PY  - 2015
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/2615
AB  - Bismuth ferrite (BiFeO3) is one of the very few materials possessing ordered both
electrical dipoles and magnetic moments in very wide range of temperatures. That gives
it tremendous opportunities for research and application.
BiFeO3 precursor powders were prepared by auto-combustion and soft chemical
synthesis methods using different organic compounds as fuels and complexing agents.
They were calcined at 600 °C for 2 h, grinded, pressed and sintered at 800 °C for 1 h
with quenching. XRD and SEM confirmed formation of very pure BiFeO3 perovskite
phase, but problem with low density, which is characteristic for BiFeO3 ceramics, still
remained. It doesn’t affect magnetic properties, but has strong influence on electrical
and, through them, on multiferroic properties. To define actual, intrinsic properties of
material, it is very important to obtain ceramics with densities close to theoretical. For
this reason, many treatments were tried in order to raise samples’ densities: powder
milling and homogenization, ultrasound, different pressures, various thermal treatments.
Powders and ceramic samples were then characterized (particle size analysis, XRD,
SEM). The densities of sintered BiFeO3 samples were measured. All the treatments had
impact on ceramics density, but some also introduced secondary phases.
PB  - Faculty of Technology, University of Novi Sad Bul. cara Lazara 1, 21000 Novi Sad, Serbia
C3  - 11th Conference for Young Scientists in Ceramics, COST Workshop Novi Sad, Serbia, October 21-24, 2015
T1  - BiFeO3 CERAMICS DENSIFICATION STUDY
UR  - https://hdl.handle.net/21.15107/rcub_rimsi_2615
ER  - 
@conference{
author = "Ilić, Nikola and Bobić, Jelena and Džunuzović, Adis and Makarović, Maja and Rojac, Tadej and Stojanović, Biljana",
year = "2015",
abstract = "Bismuth ferrite (BiFeO3) is one of the very few materials possessing ordered both
electrical dipoles and magnetic moments in very wide range of temperatures. That gives
it tremendous opportunities for research and application.
BiFeO3 precursor powders were prepared by auto-combustion and soft chemical
synthesis methods using different organic compounds as fuels and complexing agents.
They were calcined at 600 °C for 2 h, grinded, pressed and sintered at 800 °C for 1 h
with quenching. XRD and SEM confirmed formation of very pure BiFeO3 perovskite
phase, but problem with low density, which is characteristic for BiFeO3 ceramics, still
remained. It doesn’t affect magnetic properties, but has strong influence on electrical
and, through them, on multiferroic properties. To define actual, intrinsic properties of
material, it is very important to obtain ceramics with densities close to theoretical. For
this reason, many treatments were tried in order to raise samples’ densities: powder
milling and homogenization, ultrasound, different pressures, various thermal treatments.
Powders and ceramic samples were then characterized (particle size analysis, XRD,
SEM). The densities of sintered BiFeO3 samples were measured. All the treatments had
impact on ceramics density, but some also introduced secondary phases.",
publisher = "Faculty of Technology, University of Novi Sad Bul. cara Lazara 1, 21000 Novi Sad, Serbia",
journal = "11th Conference for Young Scientists in Ceramics, COST Workshop Novi Sad, Serbia, October 21-24, 2015",
title = "BiFeO3 CERAMICS DENSIFICATION STUDY",
url = "https://hdl.handle.net/21.15107/rcub_rimsi_2615"
}
Ilić, N., Bobić, J., Džunuzović, A., Makarović, M., Rojac, T.,& Stojanović, B.. (2015). BiFeO3 CERAMICS DENSIFICATION STUDY. in 11th Conference for Young Scientists in Ceramics, COST Workshop Novi Sad, Serbia, October 21-24, 2015
Faculty of Technology, University of Novi Sad Bul. cara Lazara 1, 21000 Novi Sad, Serbia..
https://hdl.handle.net/21.15107/rcub_rimsi_2615
Ilić N, Bobić J, Džunuzović A, Makarović M, Rojac T, Stojanović B. BiFeO3 CERAMICS DENSIFICATION STUDY. in 11th Conference for Young Scientists in Ceramics, COST Workshop Novi Sad, Serbia, October 21-24, 2015. 2015;.
https://hdl.handle.net/21.15107/rcub_rimsi_2615 .
Ilić, Nikola, Bobić, Jelena, Džunuzović, Adis, Makarović, Maja, Rojac, Tadej, Stojanović, Biljana, "BiFeO3 CERAMICS DENSIFICATION STUDY" in 11th Conference for Young Scientists in Ceramics, COST Workshop Novi Sad, Serbia, October 21-24, 2015 (2015),
https://hdl.handle.net/21.15107/rcub_rimsi_2615 .

IMPROVED ELECTRICAL AND MAGNETIC PROPERTIES IN Y DOPED BiFeO3 CERAMICS

Ilić, Nikola; Stojadinovic, Bojan; Džunuzović, Adis; Bobić, Jelena; Tasic, Nikola; Curecheriu, Lavinia-Petronela; Dohcevic Mitrovic, Zorana; Stojanović, Biljana

(Institute for Multidisciplinary Research, University of Belgrade Kneza Višeslava 1, 11000 Belgrade, Serbia, 2015)

TY  - CONF
AU  - Ilić, Nikola
AU  - Stojadinovic, Bojan
AU  - Džunuzović, Adis
AU  - Bobić, Jelena
AU  - Tasic, Nikola
AU  - Curecheriu, Lavinia-Petronela
AU  - Dohcevic  Mitrovic, Zorana
AU  - Stojanović, Biljana
PY  - 2015
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/2566
AB  - Bismuth ferrite (BiFeO3) is considered one of the most promising single phase multiferroic materials thanks to the fact it exhibits ferroelectric and antiferromagnetic properties in the same time in very wide range of temperatures (up to 370 °C). Difficulties in obtaining pure BiFeO3 phase and dense ceramics, together with occurrence of leakage currents have prevented application of BiFeO3.
Substitution of Bi3+ or Fe3+ ions with some transition metal or rare earth ions can
improve both electrical and magnetic properties by reducing leakage currents and introducing weak ferromagnetism through structural changes.
Y doped bismuth ferrite, Bi1-xYxFeO3, was synthesized by auto-combustion method using urea as a fuel. Precursor powders were annealed, pressed and sintered. Powders and ceramic samples were characterized by XRD, SEM, Raman, impedance spectroscopy, ferroelectric and magneticmeasurements.
X-ray diffractograms and Raman spectra showed no presence of secondary phases. SEM images indicated lowering of grain size with higher concentration of Y3+. Electrical resistance is highly improved even at 1 % of Y, while 10 % of Y was necessary to break spiral spin structure, leading to weak ferromagnetism.
PB  - Institute for Multidisciplinary Research, University of Belgrade Kneza Višeslava 1, 11000 Belgrade, Serbia
C3  - 3rd Conference of The Serbian Society for Ceramic Materials
T1  - IMPROVED ELECTRICAL AND MAGNETIC PROPERTIES IN Y DOPED BiFeO3 CERAMICS
UR  - https://hdl.handle.net/21.15107/rcub_rimsi_2566
ER  - 
@conference{
author = "Ilić, Nikola and Stojadinovic, Bojan and Džunuzović, Adis and Bobić, Jelena and Tasic, Nikola and Curecheriu, Lavinia-Petronela and Dohcevic  Mitrovic, Zorana and Stojanović, Biljana",
year = "2015",
abstract = "Bismuth ferrite (BiFeO3) is considered one of the most promising single phase multiferroic materials thanks to the fact it exhibits ferroelectric and antiferromagnetic properties in the same time in very wide range of temperatures (up to 370 °C). Difficulties in obtaining pure BiFeO3 phase and dense ceramics, together with occurrence of leakage currents have prevented application of BiFeO3.
Substitution of Bi3+ or Fe3+ ions with some transition metal or rare earth ions can
improve both electrical and magnetic properties by reducing leakage currents and introducing weak ferromagnetism through structural changes.
Y doped bismuth ferrite, Bi1-xYxFeO3, was synthesized by auto-combustion method using urea as a fuel. Precursor powders were annealed, pressed and sintered. Powders and ceramic samples were characterized by XRD, SEM, Raman, impedance spectroscopy, ferroelectric and magneticmeasurements.
X-ray diffractograms and Raman spectra showed no presence of secondary phases. SEM images indicated lowering of grain size with higher concentration of Y3+. Electrical resistance is highly improved even at 1 % of Y, while 10 % of Y was necessary to break spiral spin structure, leading to weak ferromagnetism.",
publisher = "Institute for Multidisciplinary Research, University of Belgrade Kneza Višeslava 1, 11000 Belgrade, Serbia",
journal = "3rd Conference of The Serbian Society for Ceramic Materials",
title = "IMPROVED ELECTRICAL AND MAGNETIC PROPERTIES IN Y DOPED BiFeO3 CERAMICS",
url = "https://hdl.handle.net/21.15107/rcub_rimsi_2566"
}
Ilić, N., Stojadinovic, B., Džunuzović, A., Bobić, J., Tasic, N., Curecheriu, L., Dohcevic  Mitrovic, Z.,& Stojanović, B.. (2015). IMPROVED ELECTRICAL AND MAGNETIC PROPERTIES IN Y DOPED BiFeO3 CERAMICS. in 3rd Conference of The Serbian Society for Ceramic Materials
Institute for Multidisciplinary Research, University of Belgrade Kneza Višeslava 1, 11000 Belgrade, Serbia..
https://hdl.handle.net/21.15107/rcub_rimsi_2566
Ilić N, Stojadinovic B, Džunuzović A, Bobić J, Tasic N, Curecheriu L, Dohcevic  Mitrovic Z, Stojanović B. IMPROVED ELECTRICAL AND MAGNETIC PROPERTIES IN Y DOPED BiFeO3 CERAMICS. in 3rd Conference of The Serbian Society for Ceramic Materials. 2015;.
https://hdl.handle.net/21.15107/rcub_rimsi_2566 .
Ilić, Nikola, Stojadinovic, Bojan, Džunuzović, Adis, Bobić, Jelena, Tasic, Nikola, Curecheriu, Lavinia-Petronela, Dohcevic  Mitrovic, Zorana, Stojanović, Biljana, "IMPROVED ELECTRICAL AND MAGNETIC PROPERTIES IN Y DOPED BiFeO3 CERAMICS" in 3rd Conference of The Serbian Society for Ceramic Materials (2015),
https://hdl.handle.net/21.15107/rcub_rimsi_2566 .

ELECTRICAL AND MAGNETIC PROPERTIES OF MULTIFERROIC Bi5FeTi3O15 AND Bi4.25La0.75Ti3FeO15 CERAMICS

Bobić, Jelena; Vijatović Petrović, Mirjana; Ilić, Nikola; Džunuzović, Adis; Ivanov, Maxim; Stojanović, Biljana

(Institute for Multidisciplinary Research, University of Belgrade Kneza Višeslava 1, 11000 Belgrade, Serbia, 2015)

TY  - CONF
AU  - Bobić, Jelena
AU  - Vijatović Petrović, Mirjana
AU  - Ilić, Nikola
AU  - Džunuzović, Adis
AU  - Ivanov, Maxim
AU  - Stojanović, Biljana
PY  - 2015
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/2562
AB  - Multifferioc materials exhibiting ferroelectric and magnetic orders simultaneously have attracted a lot of interest in recent years due to their special phenomena and potential applications in multifunctional devices [1]. One of the most frequently investigated single-phase multiferroic materials is perovskite BiFeO3 (BFO) but it shows weak ferromagnetics at room temperature due to its canted spin structure. Among the compounds, Bi5FeTi3O15 (BFT) ceramics can be regarded as a model of the Aurivillius type of ferroelectromagnetics.
BFT was prepared by solid state reaction methods from the constituting high purity oxides (Fe2O3, Bi2O3, TiO2 and La2O3). XRD data confirm the formation of single-phase Aurivillius compounds while SEM micrographs shows a evident decrease of grain size of La modified ceramics in comparison with pure BFT. Dielectric properties were investigated in a wide range of temperatures (300-1000
K) and frequencies (1 Hz – 1 MHz). The conductivity of sintered samples was studied, suggesting decreasing of conductivity of La modified ceramics in comparison with pure BFT. Ferroelectric and ferromagnetic measurements of both samples were also performed.
PB  - Institute for Multidisciplinary Research, University of Belgrade Kneza Višeslava 1, 11000 Belgrade, Serbia
C3  - 3rd Conference of The Serbian Society for Ceramic Materials
T1  - ELECTRICAL AND MAGNETIC PROPERTIES OF MULTIFERROIC Bi5FeTi3O15 AND Bi4.25La0.75Ti3FeO15 CERAMICS
UR  - https://hdl.handle.net/21.15107/rcub_rimsi_2562
ER  - 
@conference{
author = "Bobić, Jelena and Vijatović Petrović, Mirjana and Ilić, Nikola and Džunuzović, Adis and Ivanov, Maxim and Stojanović, Biljana",
year = "2015",
abstract = "Multifferioc materials exhibiting ferroelectric and magnetic orders simultaneously have attracted a lot of interest in recent years due to their special phenomena and potential applications in multifunctional devices [1]. One of the most frequently investigated single-phase multiferroic materials is perovskite BiFeO3 (BFO) but it shows weak ferromagnetics at room temperature due to its canted spin structure. Among the compounds, Bi5FeTi3O15 (BFT) ceramics can be regarded as a model of the Aurivillius type of ferroelectromagnetics.
BFT was prepared by solid state reaction methods from the constituting high purity oxides (Fe2O3, Bi2O3, TiO2 and La2O3). XRD data confirm the formation of single-phase Aurivillius compounds while SEM micrographs shows a evident decrease of grain size of La modified ceramics in comparison with pure BFT. Dielectric properties were investigated in a wide range of temperatures (300-1000
K) and frequencies (1 Hz – 1 MHz). The conductivity of sintered samples was studied, suggesting decreasing of conductivity of La modified ceramics in comparison with pure BFT. Ferroelectric and ferromagnetic measurements of both samples were also performed.",
publisher = "Institute for Multidisciplinary Research, University of Belgrade Kneza Višeslava 1, 11000 Belgrade, Serbia",
journal = "3rd Conference of The Serbian Society for Ceramic Materials",
title = "ELECTRICAL AND MAGNETIC PROPERTIES OF MULTIFERROIC Bi5FeTi3O15 AND Bi4.25La0.75Ti3FeO15 CERAMICS",
url = "https://hdl.handle.net/21.15107/rcub_rimsi_2562"
}
Bobić, J., Vijatović Petrović, M., Ilić, N., Džunuzović, A., Ivanov, M.,& Stojanović, B.. (2015). ELECTRICAL AND MAGNETIC PROPERTIES OF MULTIFERROIC Bi5FeTi3O15 AND Bi4.25La0.75Ti3FeO15 CERAMICS. in 3rd Conference of The Serbian Society for Ceramic Materials
Institute for Multidisciplinary Research, University of Belgrade Kneza Višeslava 1, 11000 Belgrade, Serbia..
https://hdl.handle.net/21.15107/rcub_rimsi_2562
Bobić J, Vijatović Petrović M, Ilić N, Džunuzović A, Ivanov M, Stojanović B. ELECTRICAL AND MAGNETIC PROPERTIES OF MULTIFERROIC Bi5FeTi3O15 AND Bi4.25La0.75Ti3FeO15 CERAMICS. in 3rd Conference of The Serbian Society for Ceramic Materials. 2015;.
https://hdl.handle.net/21.15107/rcub_rimsi_2562 .
Bobić, Jelena, Vijatović Petrović, Mirjana, Ilić, Nikola, Džunuzović, Adis, Ivanov, Maxim, Stojanović, Biljana, "ELECTRICAL AND MAGNETIC PROPERTIES OF MULTIFERROIC Bi5FeTi3O15 AND Bi4.25La0.75Ti3FeO15 CERAMICS" in 3rd Conference of The Serbian Society for Ceramic Materials (2015),
https://hdl.handle.net/21.15107/rcub_rimsi_2562 .

AUTOCOMBUSTION SYNTHESIS AND CHARACTERIZATION OF MULTIFERROIC BISMUTH FERRITE CERAMICS

Ilić, Nikola; Džunuzović, Adis; Bobić, Jelena; Vijatović Petrović, Mirjana; Stojanović, Biljana

(Faculty of Technology, University of Novi Sad Bul. cara Lazara 1, 21000 Novi Sad, Serbia, 2013)

TY  - CONF
AU  - Ilić, Nikola
AU  - Džunuzović, Adis
AU  - Bobić, Jelena
AU  - Vijatović Petrović, Mirjana
AU  - Stojanović, Biljana
PY  - 2013
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/2624
AB  - Bismuth ferrite is one of the most promising single multiferroic materials. It exhibits ferroelectric and antiferromagnetic behavior in wide range of temperatures. Many new applications arise due to possibility of magnetization reorientation by electric field and polarization reorientation by magnetic field [1]. Main problem in usage of BiFeO3 is difficulty of obtaining pure phase ceramic and high conductivity as a result of Fe non-stoichiometry.
BiFeO3 (BFO) powders were prepared by auto-combustion and soft chemical methods starting from iron and bismuth nitrates. After the synthesis, fine precursor powders were thermally treated for various periods at different temperatures and heating rates. In case of auto-combustion synthesis, several fuels (citric acid, sucrose and urea) and fuel to oxidizer ratios (F/O) were examined, while for soft chemical synthesis two complexing agents were tested: citric and tartaric acids. Low temperature synthesis was also tested without any complexing agent. XRD measurements showed presence of Bi2O3, Bi2Fe4O9 and Bi25FeO39 secondary phases in all powders, and pure perovskite BFO phase for several sintered samples. Powders and ceramics were characterized by SEM/EDS, TG/DTA, particle size distribution and BET surface area measurements. Impedance and magnetic measurements were performed in order to define electrical and magnetic properties of BFO ceramics.
PB  - Faculty of Technology, University of Novi Sad Bul. cara Lazara 1, 21000 Novi Sad, Serbia
C3  - The Third Early Stage Researchers Workshop” COST MP0904 - SIMUFER Novi Sad, Serbia, November 6-9, 2013
T1  - AUTOCOMBUSTION SYNTHESIS AND CHARACTERIZATION OF MULTIFERROIC BISMUTH FERRITE CERAMICS
UR  - https://hdl.handle.net/21.15107/rcub_rimsi_2624
ER  - 
@conference{
author = "Ilić, Nikola and Džunuzović, Adis and Bobić, Jelena and Vijatović Petrović, Mirjana and Stojanović, Biljana",
year = "2013",
abstract = "Bismuth ferrite is one of the most promising single multiferroic materials. It exhibits ferroelectric and antiferromagnetic behavior in wide range of temperatures. Many new applications arise due to possibility of magnetization reorientation by electric field and polarization reorientation by magnetic field [1]. Main problem in usage of BiFeO3 is difficulty of obtaining pure phase ceramic and high conductivity as a result of Fe non-stoichiometry.
BiFeO3 (BFO) powders were prepared by auto-combustion and soft chemical methods starting from iron and bismuth nitrates. After the synthesis, fine precursor powders were thermally treated for various periods at different temperatures and heating rates. In case of auto-combustion synthesis, several fuels (citric acid, sucrose and urea) and fuel to oxidizer ratios (F/O) were examined, while for soft chemical synthesis two complexing agents were tested: citric and tartaric acids. Low temperature synthesis was also tested without any complexing agent. XRD measurements showed presence of Bi2O3, Bi2Fe4O9 and Bi25FeO39 secondary phases in all powders, and pure perovskite BFO phase for several sintered samples. Powders and ceramics were characterized by SEM/EDS, TG/DTA, particle size distribution and BET surface area measurements. Impedance and magnetic measurements were performed in order to define electrical and magnetic properties of BFO ceramics.",
publisher = "Faculty of Technology, University of Novi Sad Bul. cara Lazara 1, 21000 Novi Sad, Serbia",
journal = "The Third Early Stage Researchers Workshop” COST MP0904 - SIMUFER Novi Sad, Serbia, November 6-9, 2013",
title = "AUTOCOMBUSTION SYNTHESIS AND CHARACTERIZATION OF MULTIFERROIC BISMUTH FERRITE CERAMICS",
url = "https://hdl.handle.net/21.15107/rcub_rimsi_2624"
}
Ilić, N., Džunuzović, A., Bobić, J., Vijatović Petrović, M.,& Stojanović, B.. (2013). AUTOCOMBUSTION SYNTHESIS AND CHARACTERIZATION OF MULTIFERROIC BISMUTH FERRITE CERAMICS. in The Third Early Stage Researchers Workshop” COST MP0904 - SIMUFER Novi Sad, Serbia, November 6-9, 2013
Faculty of Technology, University of Novi Sad Bul. cara Lazara 1, 21000 Novi Sad, Serbia..
https://hdl.handle.net/21.15107/rcub_rimsi_2624
Ilić N, Džunuzović A, Bobić J, Vijatović Petrović M, Stojanović B. AUTOCOMBUSTION SYNTHESIS AND CHARACTERIZATION OF MULTIFERROIC BISMUTH FERRITE CERAMICS. in The Third Early Stage Researchers Workshop” COST MP0904 - SIMUFER Novi Sad, Serbia, November 6-9, 2013. 2013;.
https://hdl.handle.net/21.15107/rcub_rimsi_2624 .
Ilić, Nikola, Džunuzović, Adis, Bobić, Jelena, Vijatović Petrović, Mirjana, Stojanović, Biljana, "AUTOCOMBUSTION SYNTHESIS AND CHARACTERIZATION OF MULTIFERROIC BISMUTH FERRITE CERAMICS" in The Third Early Stage Researchers Workshop” COST MP0904 - SIMUFER Novi Sad, Serbia, November 6-9, 2013 (2013),
https://hdl.handle.net/21.15107/rcub_rimsi_2624 .

Chemical synthesis of nanocrystalline CuAlO2 via nitrate-citrate combustion route

Vojisavljević, Katarina; Stojanović, Biljana; Kmet, Brigita; Cilenšek, Jena; Malič, Barbara

(Maribor : Fakulteta za kemijo in kemijsko tehnologijo, 2013)

TY  - CONF
AU  - Vojisavljević, Katarina
AU  - Stojanović, Biljana
AU  - Kmet, Brigita
AU  - Cilenšek, Jena
AU  - Malič, Barbara
PY  - 2013
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/2901
AB  - The nanocrystalline delafossite CuAlO2 powder was synthesised by a sol-gel nitrate-citrate self-combustion route. Citric acid was introduced both as the chelating and reducing agent or fuel. The citric acid/metal ion ratio was adjusted to provide fuel-lean, stoichiometric or fuel-rich conditions of the redox reaction. Equimolar amounts of copper and aluminium nitrates and the citric acid were dissolved in deionized water. The sol was dried at 80 oC to obtain the gel. By increasing the temperature above 250 oC, the gel immediately ignited, forming the precursor powder. According to the X-ray diffraction analysis the phase pure delafossite was obtained only when the precursor powder was prepared from the stoichiometric redox reaction, and after the calcination for 4 h in Ar atmosphere at 920 oC. The field emission scanning electron micrographs revealed the cauliflower aspect of the calcined powder, where small primary particles formed the agglomerates. The formation of the phase pure CuAlO2 powder was also confirmed by Fourier transformed infrared spectroscopy.
PB  - Maribor : Fakulteta za kemijo in kemijsko tehnologijo
C3  - Slovenski kemijski dnevi 2013
T1  - Chemical synthesis of nanocrystalline CuAlO2 via nitrate-citrate combustion route
IS  - 7
UR  - https://hdl.handle.net/21.15107/rcub_rimsi_2901
ER  - 
@conference{
author = "Vojisavljević, Katarina and Stojanović, Biljana and Kmet, Brigita and Cilenšek, Jena and Malič, Barbara",
year = "2013",
abstract = "The nanocrystalline delafossite CuAlO2 powder was synthesised by a sol-gel nitrate-citrate self-combustion route. Citric acid was introduced both as the chelating and reducing agent or fuel. The citric acid/metal ion ratio was adjusted to provide fuel-lean, stoichiometric or fuel-rich conditions of the redox reaction. Equimolar amounts of copper and aluminium nitrates and the citric acid were dissolved in deionized water. The sol was dried at 80 oC to obtain the gel. By increasing the temperature above 250 oC, the gel immediately ignited, forming the precursor powder. According to the X-ray diffraction analysis the phase pure delafossite was obtained only when the precursor powder was prepared from the stoichiometric redox reaction, and after the calcination for 4 h in Ar atmosphere at 920 oC. The field emission scanning electron micrographs revealed the cauliflower aspect of the calcined powder, where small primary particles formed the agglomerates. The formation of the phase pure CuAlO2 powder was also confirmed by Fourier transformed infrared spectroscopy.",
publisher = "Maribor : Fakulteta za kemijo in kemijsko tehnologijo",
journal = "Slovenski kemijski dnevi 2013",
title = "Chemical synthesis of nanocrystalline CuAlO2 via nitrate-citrate combustion route",
number = "7",
url = "https://hdl.handle.net/21.15107/rcub_rimsi_2901"
}
Vojisavljević, K., Stojanović, B., Kmet, B., Cilenšek, J.,& Malič, B.. (2013). Chemical synthesis of nanocrystalline CuAlO2 via nitrate-citrate combustion route. in Slovenski kemijski dnevi 2013
Maribor : Fakulteta za kemijo in kemijsko tehnologijo.(7).
https://hdl.handle.net/21.15107/rcub_rimsi_2901
Vojisavljević K, Stojanović B, Kmet B, Cilenšek J, Malič B. Chemical synthesis of nanocrystalline CuAlO2 via nitrate-citrate combustion route. in Slovenski kemijski dnevi 2013. 2013;(7).
https://hdl.handle.net/21.15107/rcub_rimsi_2901 .
Vojisavljević, Katarina, Stojanović, Biljana, Kmet, Brigita, Cilenšek, Jena, Malič, Barbara, "Chemical synthesis of nanocrystalline CuAlO2 via nitrate-citrate combustion route" in Slovenski kemijski dnevi 2013, no. 7 (2013),
https://hdl.handle.net/21.15107/rcub_rimsi_2901 .

RELAXOR BEHAVIOR OF BaBi4Ti4O15

Bobić, Jelena; Vijatović Petrović, Mirjana; Greičius, S.; Banys, Juras; Stojanović, Biljana

(The Serbian Ceramic Society Vinča Institute of Nuclear Sciences, University of Belgrade Institute for Multidisciplinary Research, University of Belgrade Institute of Physics, University of Belgrade, 2011)

TY  - CONF
AU  - Bobić, Jelena
AU  - Vijatović Petrović, Mirjana
AU  - Greičius, S.
AU  - Banys, Juras
AU  - Stojanović, Biljana
PY  - 2011
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/2656
AB  - Dense BaBi4Ti4O15 ceramics were prepared by conventional solid state reaction
from appropriate oxide mixture. Dielectric properties were investigated in a wide range
of temperatures and frequencies. A modified Curie-Weiss relationship is used to study
the diffuseness behavior of a ferroelectric phase transition. The dielectric relaxation rate
follows the Vogel-Fulcher relation with Ea = 0.013 eV, ν0 = 2.09 ×108 Hz and Tf = 651 K.
Impedance investigations show only a single semicircle which can be ascribed to the
grain component for all investigated temperatures. The calculated values of activation
energy Ea is 1.02 eV.
PB  - The Serbian Ceramic Society Vinča Institute of Nuclear Sciences, University of Belgrade Institute for Multidisciplinary Research, University of Belgrade Institute of Physics, University of Belgrade
C3  - 1st Conference of the Serbian Ceramic Society, March 17-18. 2011. Belgrade, Serbia 1CSCS-2011
T1  - RELAXOR BEHAVIOR OF BaBi4Ti4O15
UR  - https://hdl.handle.net/21.15107/rcub_rimsi_2656
ER  - 
@conference{
author = "Bobić, Jelena and Vijatović Petrović, Mirjana and Greičius, S. and Banys, Juras and Stojanović, Biljana",
year = "2011",
abstract = "Dense BaBi4Ti4O15 ceramics were prepared by conventional solid state reaction
from appropriate oxide mixture. Dielectric properties were investigated in a wide range
of temperatures and frequencies. A modified Curie-Weiss relationship is used to study
the diffuseness behavior of a ferroelectric phase transition. The dielectric relaxation rate
follows the Vogel-Fulcher relation with Ea = 0.013 eV, ν0 = 2.09 ×108 Hz and Tf = 651 K.
Impedance investigations show only a single semicircle which can be ascribed to the
grain component for all investigated temperatures. The calculated values of activation
energy Ea is 1.02 eV.",
publisher = "The Serbian Ceramic Society Vinča Institute of Nuclear Sciences, University of Belgrade Institute for Multidisciplinary Research, University of Belgrade Institute of Physics, University of Belgrade",
journal = "1st Conference of the Serbian Ceramic Society, March 17-18. 2011. Belgrade, Serbia 1CSCS-2011",
title = "RELAXOR BEHAVIOR OF BaBi4Ti4O15",
url = "https://hdl.handle.net/21.15107/rcub_rimsi_2656"
}
Bobić, J., Vijatović Petrović, M., Greičius, S., Banys, J.,& Stojanović, B.. (2011). RELAXOR BEHAVIOR OF BaBi4Ti4O15. in 1st Conference of the Serbian Ceramic Society, March 17-18. 2011. Belgrade, Serbia 1CSCS-2011
The Serbian Ceramic Society Vinča Institute of Nuclear Sciences, University of Belgrade Institute for Multidisciplinary Research, University of Belgrade Institute of Physics, University of Belgrade..
https://hdl.handle.net/21.15107/rcub_rimsi_2656
Bobić J, Vijatović Petrović M, Greičius S, Banys J, Stojanović B. RELAXOR BEHAVIOR OF BaBi4Ti4O15. in 1st Conference of the Serbian Ceramic Society, March 17-18. 2011. Belgrade, Serbia 1CSCS-2011. 2011;.
https://hdl.handle.net/21.15107/rcub_rimsi_2656 .
Bobić, Jelena, Vijatović Petrović, Mirjana, Greičius, S., Banys, Juras, Stojanović, Biljana, "RELAXOR BEHAVIOR OF BaBi4Ti4O15" in 1st Conference of the Serbian Ceramic Society, March 17-18. 2011. Belgrade, Serbia 1CSCS-2011 (2011),
https://hdl.handle.net/21.15107/rcub_rimsi_2656 .

CHARACTERIZATION OF BARIUM BISMUTH TITANATE OBTAINED BY MECHANOCHEMICAL SYNTHESIS

Lazarevic, Zorica; Bobić, Jelena; Romcevic, Nebojsa; Stojanović, Biljana

(The Serbian Ceramic Society Vinča Institute of Nuclear Sciences, University of Belgrade Institute for Multidisciplinary Research, University of Belgrade Institute of Physics, University of Belgrade, 2011)

TY  - CONF
AU  - Lazarevic, Zorica
AU  - Bobić, Jelena
AU  - Romcevic, Nebojsa
AU  - Stojanović, Biljana
PY  - 2011
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/2655
AB  - Barium bismuth titanate, BaBi4Ti4O15 (BBT) was prepared by homogenization and
sintering of mixture of stoichiometric quantities of BaTiO3 and Bi4Ti3O12 obtained via
mechanochemical synthesis. The reaction mechanism of BaBi4Ti4O15 formation and the
characteristics of BBT powders and ceramics were studied using XRD, Raman
spectroscopy and SEM. The results confirmed that BaBi4Ti4O15 was formed by
tetragonal symmetry. Only 4 Raman modes are clearly observed. Ba2+ ions randomly
occupy the Bi sites of a pseudo-perovskite layer and may enter in a bismuth oxide layer.
BaBi4Ti4O15 ceramics possess the plate-like structure typical for layered structure
materials.
PB  - The Serbian Ceramic Society Vinča Institute of Nuclear Sciences, University of Belgrade Institute for Multidisciplinary Research, University of Belgrade Institute of Physics, University of Belgrade
C3  - 1st Conference of the Serbian Ceramic Society, March 17-18. 2011. Belgrade, Serbia 1CSCS-2011
T1  - CHARACTERIZATION OF BARIUM BISMUTH TITANATE OBTAINED BY MECHANOCHEMICAL SYNTHESIS
UR  - https://hdl.handle.net/21.15107/rcub_rimsi_2655
ER  - 
@conference{
author = "Lazarevic, Zorica and Bobić, Jelena and Romcevic, Nebojsa and Stojanović, Biljana",
year = "2011",
abstract = "Barium bismuth titanate, BaBi4Ti4O15 (BBT) was prepared by homogenization and
sintering of mixture of stoichiometric quantities of BaTiO3 and Bi4Ti3O12 obtained via
mechanochemical synthesis. The reaction mechanism of BaBi4Ti4O15 formation and the
characteristics of BBT powders and ceramics were studied using XRD, Raman
spectroscopy and SEM. The results confirmed that BaBi4Ti4O15 was formed by
tetragonal symmetry. Only 4 Raman modes are clearly observed. Ba2+ ions randomly
occupy the Bi sites of a pseudo-perovskite layer and may enter in a bismuth oxide layer.
BaBi4Ti4O15 ceramics possess the plate-like structure typical for layered structure
materials.",
publisher = "The Serbian Ceramic Society Vinča Institute of Nuclear Sciences, University of Belgrade Institute for Multidisciplinary Research, University of Belgrade Institute of Physics, University of Belgrade",
journal = "1st Conference of the Serbian Ceramic Society, March 17-18. 2011. Belgrade, Serbia 1CSCS-2011",
title = "CHARACTERIZATION OF BARIUM BISMUTH TITANATE OBTAINED BY MECHANOCHEMICAL SYNTHESIS",
url = "https://hdl.handle.net/21.15107/rcub_rimsi_2655"
}
Lazarevic, Z., Bobić, J., Romcevic, N.,& Stojanović, B.. (2011). CHARACTERIZATION OF BARIUM BISMUTH TITANATE OBTAINED BY MECHANOCHEMICAL SYNTHESIS. in 1st Conference of the Serbian Ceramic Society, March 17-18. 2011. Belgrade, Serbia 1CSCS-2011
The Serbian Ceramic Society Vinča Institute of Nuclear Sciences, University of Belgrade Institute for Multidisciplinary Research, University of Belgrade Institute of Physics, University of Belgrade..
https://hdl.handle.net/21.15107/rcub_rimsi_2655
Lazarevic Z, Bobić J, Romcevic N, Stojanović B. CHARACTERIZATION OF BARIUM BISMUTH TITANATE OBTAINED BY MECHANOCHEMICAL SYNTHESIS. in 1st Conference of the Serbian Ceramic Society, March 17-18. 2011. Belgrade, Serbia 1CSCS-2011. 2011;.
https://hdl.handle.net/21.15107/rcub_rimsi_2655 .
Lazarevic, Zorica, Bobić, Jelena, Romcevic, Nebojsa, Stojanović, Biljana, "CHARACTERIZATION OF BARIUM BISMUTH TITANATE OBTAINED BY MECHANOCHEMICAL SYNTHESIS" in 1st Conference of the Serbian Ceramic Society, March 17-18. 2011. Belgrade, Serbia 1CSCS-2011 (2011),
https://hdl.handle.net/21.15107/rcub_rimsi_2655 .

Characterization of Barium Titanate powders Prepared by polymeric Precursors Method

Vijatović Petrović, Mirjana; Bobić, Jelena; Stojanović, Biljana; Bowen, Paul

(COST Action 539 - ELENA NanoMetro Workshop, Leysin, January 31,2008, 2008)

TY  - CONF
AU  - Vijatović Petrović, Mirjana
AU  - Bobić, Jelena
AU  - Stojanović, Biljana
AU  - Bowen, Paul
PY  - 2008
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/2694
AB  - Barium titanate is the first ferro-electric ceramics and good candidate for variety applications due to its excellent dielectric, ferroelectric and piezoelectric properties. Barium titanate is a member of large family of compound with general formula ABO3 which is called perovskite. Barium titanate is the first discovered ferroelectric perovskite. Doping of BaTiO3 is very important for obtaining very interesting characteristic for various application. Barium titanate is normally an insulator but after doping with trivalent donor  such as La it becomes semi-conductive.
Synthesis method depends of the desired characteristic for the end application and it was distinguish a significant influence of used method on structure and properties of barium titanate materials.
From the experimental results it can be concluded that powders of barium titanate
obtained by Pechini process are nanosized. SEM observation indicates that higher percentage
of La inhibits grain growth in doped barium titanate.
Particle size distribution measurement pointed that the powders are highly
agglomerated. Figure 2. shows particle size distribution for pure barium titanate powder. The
next step in our work will be addressed to reducing the particle size by attrition milling with
zironia media and these results will be presented and discussed.
PB  - COST Action 539 - ELENA NanoMetro Workshop, Leysin, January 31,2008
C3  - COST Action 539 - ELENA NanoMetro Workshop, Leysin, January 31,2008
T1  - Characterization of Barium Titanate powders Prepared by polymeric Precursors Method
UR  - https://hdl.handle.net/21.15107/rcub_rimsi_2694
ER  - 
@conference{
author = "Vijatović Petrović, Mirjana and Bobić, Jelena and Stojanović, Biljana and Bowen, Paul",
year = "2008",
abstract = "Barium titanate is the first ferro-electric ceramics and good candidate for variety applications due to its excellent dielectric, ferroelectric and piezoelectric properties. Barium titanate is a member of large family of compound with general formula ABO3 which is called perovskite. Barium titanate is the first discovered ferroelectric perovskite. Doping of BaTiO3 is very important for obtaining very interesting characteristic for various application. Barium titanate is normally an insulator but after doping with trivalent donor  such as La it becomes semi-conductive.
Synthesis method depends of the desired characteristic for the end application and it was distinguish a significant influence of used method on structure and properties of barium titanate materials.
From the experimental results it can be concluded that powders of barium titanate
obtained by Pechini process are nanosized. SEM observation indicates that higher percentage
of La inhibits grain growth in doped barium titanate.
Particle size distribution measurement pointed that the powders are highly
agglomerated. Figure 2. shows particle size distribution for pure barium titanate powder. The
next step in our work will be addressed to reducing the particle size by attrition milling with
zironia media and these results will be presented and discussed.",
publisher = "COST Action 539 - ELENA NanoMetro Workshop, Leysin, January 31,2008",
journal = "COST Action 539 - ELENA NanoMetro Workshop, Leysin, January 31,2008",
title = "Characterization of Barium Titanate powders Prepared by polymeric Precursors Method",
url = "https://hdl.handle.net/21.15107/rcub_rimsi_2694"
}
Vijatović Petrović, M., Bobić, J., Stojanović, B.,& Bowen, P.. (2008). Characterization of Barium Titanate powders Prepared by polymeric Precursors Method. in COST Action 539 - ELENA NanoMetro Workshop, Leysin, January 31,2008
COST Action 539 - ELENA NanoMetro Workshop, Leysin, January 31,2008..
https://hdl.handle.net/21.15107/rcub_rimsi_2694
Vijatović Petrović M, Bobić J, Stojanović B, Bowen P. Characterization of Barium Titanate powders Prepared by polymeric Precursors Method. in COST Action 539 - ELENA NanoMetro Workshop, Leysin, January 31,2008. 2008;.
https://hdl.handle.net/21.15107/rcub_rimsi_2694 .
Vijatović Petrović, Mirjana, Bobić, Jelena, Stojanović, Biljana, Bowen, Paul, "Characterization of Barium Titanate powders Prepared by polymeric Precursors Method" in COST Action 539 - ELENA NanoMetro Workshop, Leysin, January 31,2008 (2008),
https://hdl.handle.net/21.15107/rcub_rimsi_2694 .

RAMAN STUDY OF FERROELECTRIC BISMUTH LAYER-OXIDE ABi4Ti4O15 PREPARED BY THE MECHANOCHEMICAL SYNTHESIS

Lazarevic, Zorica; Romcevic, Nebojsa; Bobić, Jelena; Paunovic, N; Dohcevic Mitrovic, Zorana; Stojanović, Biljana

(Workshop Fabrication, Properties & Applications of Electroceramic Nanostructures, Abstracts June 26-28,2008 Genoa, Italy, 2008)

TY  - CONF
AU  - Lazarevic, Zorica
AU  - Romcevic, Nebojsa
AU  - Bobić, Jelena
AU  - Paunovic, N
AU  - Dohcevic  Mitrovic, Zorana
AU  - Stojanović, Biljana
PY  - 2008
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/2689
AB  - Ferroelectric materials have innumerable properties related totheir spontaneus 
polarization, for instance. pyre- and piezoelectricity, which are used for various sensors and
actuators il 1. BaBi4Ti4O12 (BBT) is an r : 4 member of the Bi-layer structured ferroelecrtric
oxide family (Auriviltius phase) [2]. Bi-layered structure ferroelectric material - bismuth
titanate, Bi+Ti:Orz (BIT) and barium-bismuth titanate, BaBi+Ti+Ors (BBT) ceramic powders
were prepared by mechanical synthesis possess. BaBi+TiaOrs was prepared from stoichometric quantities of barium titanate and bismuth titanate obtained via mechanochemical
synthesis. Barium titanate, BaTiOt has been synthesised from mixture of BaO and TiGz and
bismuth titanate, Bi+TirOr: was prepared starting from BiuO: and TiOz, comercialy
available. The reaction mechanism of BBT and the preparation and characteristics of BBT ceramic
powders u,ere studied using X-ray diffraction (XRD) and IR spectroscopy The
phonon modes have been studied by Rarran spectroscopy. The Bi-layered perovskite
structure of BBT cerantic fbrrns at ll00 "C. Microstructure of Bi+Ti:Or1 is in accordiance
with the vierv that Bi,rTilOr:exhibits plate-like grains with thr average grain size increasing
u,,ith the sintering temperature. lt is eviclent that Ba2- aclition leads to the change in the
microstructure development, particularly in the change of the average grain size an;
homogeneity of the grains of BaBi4Ti4O12.
PB  - Workshop Fabrication, Properties & Applications of Electroceramic Nanostructures, Abstracts June 26-28,2008 Genoa, Italy
C3  - 4'n Workshop Fabrication, Properties & Applications of Electroceramic Nanostructures, Abstracts June 26-28,2008 Genoa, Italy
T1  - RAMAN STUDY OF FERROELECTRIC BISMUTH LAYER-OXIDE ABi4Ti4O15 PREPARED BY THE MECHANOCHEMICAL SYNTHESIS
UR  - https://hdl.handle.net/21.15107/rcub_rimsi_2689
ER  - 
@conference{
author = "Lazarevic, Zorica and Romcevic, Nebojsa and Bobić, Jelena and Paunovic, N and Dohcevic  Mitrovic, Zorana and Stojanović, Biljana",
year = "2008",
abstract = "Ferroelectric materials have innumerable properties related totheir spontaneus 
polarization, for instance. pyre- and piezoelectricity, which are used for various sensors and
actuators il 1. BaBi4Ti4O12 (BBT) is an r : 4 member of the Bi-layer structured ferroelecrtric
oxide family (Auriviltius phase) [2]. Bi-layered structure ferroelectric material - bismuth
titanate, Bi+Ti:Orz (BIT) and barium-bismuth titanate, BaBi+Ti+Ors (BBT) ceramic powders
were prepared by mechanical synthesis possess. BaBi+TiaOrs was prepared from stoichometric quantities of barium titanate and bismuth titanate obtained via mechanochemical
synthesis. Barium titanate, BaTiOt has been synthesised from mixture of BaO and TiGz and
bismuth titanate, Bi+TirOr: was prepared starting from BiuO: and TiOz, comercialy
available. The reaction mechanism of BBT and the preparation and characteristics of BBT ceramic
powders u,ere studied using X-ray diffraction (XRD) and IR spectroscopy The
phonon modes have been studied by Rarran spectroscopy. The Bi-layered perovskite
structure of BBT cerantic fbrrns at ll00 "C. Microstructure of Bi+Ti:Or1 is in accordiance
with the vierv that Bi,rTilOr:exhibits plate-like grains with thr average grain size increasing
u,,ith the sintering temperature. lt is eviclent that Ba2- aclition leads to the change in the
microstructure development, particularly in the change of the average grain size an;
homogeneity of the grains of BaBi4Ti4O12.",
publisher = "Workshop Fabrication, Properties & Applications of Electroceramic Nanostructures, Abstracts June 26-28,2008 Genoa, Italy",
journal = "4'n Workshop Fabrication, Properties & Applications of Electroceramic Nanostructures, Abstracts June 26-28,2008 Genoa, Italy",
title = "RAMAN STUDY OF FERROELECTRIC BISMUTH LAYER-OXIDE ABi4Ti4O15 PREPARED BY THE MECHANOCHEMICAL SYNTHESIS",
url = "https://hdl.handle.net/21.15107/rcub_rimsi_2689"
}
Lazarevic, Z., Romcevic, N., Bobić, J., Paunovic, N., Dohcevic  Mitrovic, Z.,& Stojanović, B.. (2008). RAMAN STUDY OF FERROELECTRIC BISMUTH LAYER-OXIDE ABi4Ti4O15 PREPARED BY THE MECHANOCHEMICAL SYNTHESIS. in 4'n Workshop Fabrication, Properties & Applications of Electroceramic Nanostructures, Abstracts June 26-28,2008 Genoa, Italy
Workshop Fabrication, Properties & Applications of Electroceramic Nanostructures, Abstracts June 26-28,2008 Genoa, Italy..
https://hdl.handle.net/21.15107/rcub_rimsi_2689
Lazarevic Z, Romcevic N, Bobić J, Paunovic N, Dohcevic  Mitrovic Z, Stojanović B. RAMAN STUDY OF FERROELECTRIC BISMUTH LAYER-OXIDE ABi4Ti4O15 PREPARED BY THE MECHANOCHEMICAL SYNTHESIS. in 4'n Workshop Fabrication, Properties & Applications of Electroceramic Nanostructures, Abstracts June 26-28,2008 Genoa, Italy. 2008;.
https://hdl.handle.net/21.15107/rcub_rimsi_2689 .
Lazarevic, Zorica, Romcevic, Nebojsa, Bobić, Jelena, Paunovic, N, Dohcevic  Mitrovic, Zorana, Stojanović, Biljana, "RAMAN STUDY OF FERROELECTRIC BISMUTH LAYER-OXIDE ABi4Ti4O15 PREPARED BY THE MECHANOCHEMICAL SYNTHESIS" in 4'n Workshop Fabrication, Properties & Applications of Electroceramic Nanostructures, Abstracts June 26-28,2008 Genoa, Italy (2008),
https://hdl.handle.net/21.15107/rcub_rimsi_2689 .

Structure and Properties of Barium Bismuth Titanate Prepared by Mechanochemical Synthesis

Bobić, Jelena; Paiva-Santos, C. O.; Jovalekic, Cedomir; Vijatović Petrović, Mirjana; Stojanović, Biljana

(11th European Meeting on Ferroelectricity, Bled, Slovenia, 3-7 September 2007, 2007)

TY  - CONF
AU  - Bobić, Jelena
AU  - Paiva-Santos, C. O.
AU  - Jovalekic, Cedomir
AU  - Vijatović Petrović, Mirjana
AU  - Stojanović, Biljana
PY  - 2007
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/2685
AB  - Recently there has been renewed interest in the properties
of the Aurivillius phases as temperature-stable ferropiezoelectrics
[1 ]. Several bismuth-layered crystal structures
and their properties have been investigated in detail [2].
However, a lot of aspects of the preparation and properties of
barium bismuth titanate remain unexplored, whereas being
promising candidate for memory applications.
In present work barium bismuth titanate (BaBi4Ti4Ors-
BBT) was prepared from stoichiometric quantities of barium
titanate and bismuth titanate obtained via mechanochemical
synthesis. Barium titanate (BaTiO3-BT) has been synthesised
from mixture of BaO and TiO2 and bismuth titanate
(Bi4Ti3Or2-BIT) was prepared starling from Bi2O3 and TiO2,
commercially available. \4echanochemical synthesis was
performed in air atmosphere in a planetary ball mill, for BT
during 60 min and for BIT during 360 min. Milling conditions
were: zirconium oxide jars and zirconium oxide balls, ball-to-powder
weight ration 20:7 and determined basic disc and
disc with jars rotation speed. The powder mixture of BT and
BIT was homogenized for 60 min.
BaEli4Ti4ols ceramics were sintered at 1100'C for 2, 4
and 12 hours without pre-calcination step. The heating rate
was 1OoC/min. The formation of phase and crystal structure of
BaTiO3, Bi4Ti3O12 and BaBiaTiaOl5 were approved by XRD
analysis. The morphology of obtained powders and
microstructure were examined by SEM method. The
electrical properties of sintered samples were carried out.
PB  - 11th European Meeting on Ferroelectricity, Bled, Slovenia, 3-7 September 2007
C3  - 11th European Meeting on Ferroelectricity, Bled, Slovenia, 3-7 September 2007
T1  - Structure and Properties of Barium Bismuth Titanate Prepared by Mechanochemical Synthesis
UR  - https://hdl.handle.net/21.15107/rcub_rimsi_2685
ER  - 
@conference{
author = "Bobić, Jelena and Paiva-Santos, C. O. and Jovalekic, Cedomir and Vijatović Petrović, Mirjana and Stojanović, Biljana",
year = "2007",
abstract = "Recently there has been renewed interest in the properties
of the Aurivillius phases as temperature-stable ferropiezoelectrics
[1 ]. Several bismuth-layered crystal structures
and their properties have been investigated in detail [2].
However, a lot of aspects of the preparation and properties of
barium bismuth titanate remain unexplored, whereas being
promising candidate for memory applications.
In present work barium bismuth titanate (BaBi4Ti4Ors-
BBT) was prepared from stoichiometric quantities of barium
titanate and bismuth titanate obtained via mechanochemical
synthesis. Barium titanate (BaTiO3-BT) has been synthesised
from mixture of BaO and TiO2 and bismuth titanate
(Bi4Ti3Or2-BIT) was prepared starling from Bi2O3 and TiO2,
commercially available. \4echanochemical synthesis was
performed in air atmosphere in a planetary ball mill, for BT
during 60 min and for BIT during 360 min. Milling conditions
were: zirconium oxide jars and zirconium oxide balls, ball-to-powder
weight ration 20:7 and determined basic disc and
disc with jars rotation speed. The powder mixture of BT and
BIT was homogenized for 60 min.
BaEli4Ti4ols ceramics were sintered at 1100'C for 2, 4
and 12 hours without pre-calcination step. The heating rate
was 1OoC/min. The formation of phase and crystal structure of
BaTiO3, Bi4Ti3O12 and BaBiaTiaOl5 were approved by XRD
analysis. The morphology of obtained powders and
microstructure were examined by SEM method. The
electrical properties of sintered samples were carried out.",
publisher = "11th European Meeting on Ferroelectricity, Bled, Slovenia, 3-7 September 2007",
journal = "11th European Meeting on Ferroelectricity, Bled, Slovenia, 3-7 September 2007",
title = "Structure and Properties of Barium Bismuth Titanate Prepared by Mechanochemical Synthesis",
url = "https://hdl.handle.net/21.15107/rcub_rimsi_2685"
}
Bobić, J., Paiva-Santos, C. O., Jovalekic, C., Vijatović Petrović, M.,& Stojanović, B.. (2007). Structure and Properties of Barium Bismuth Titanate Prepared by Mechanochemical Synthesis. in 11th European Meeting on Ferroelectricity, Bled, Slovenia, 3-7 September 2007
11th European Meeting on Ferroelectricity, Bled, Slovenia, 3-7 September 2007..
https://hdl.handle.net/21.15107/rcub_rimsi_2685
Bobić J, Paiva-Santos CO, Jovalekic C, Vijatović Petrović M, Stojanović B. Structure and Properties of Barium Bismuth Titanate Prepared by Mechanochemical Synthesis. in 11th European Meeting on Ferroelectricity, Bled, Slovenia, 3-7 September 2007. 2007;.
https://hdl.handle.net/21.15107/rcub_rimsi_2685 .
Bobić, Jelena, Paiva-Santos, C. O., Jovalekic, Cedomir, Vijatović Petrović, Mirjana, Stojanović, Biljana, "Structure and Properties of Barium Bismuth Titanate Prepared by Mechanochemical Synthesis" in 11th European Meeting on Ferroelectricity, Bled, Slovenia, 3-7 September 2007 (2007),
https://hdl.handle.net/21.15107/rcub_rimsi_2685 .

EFFECT OF LANTHANUM ON MICROSTRUCTURE OF BaTiO3: PREPARED BY POLYMERIC PRECURSORS METHOD

Vijatović Petrović, Mirjana; Bobić, Jelena; Cilense, Mario; Zivkovic, Ljiljana; Stojanović, Biljana

(3'd Workshop Nanostructured Materials : Processing and Application September 2, 2007 Bled, Slovenia, 2007)

TY  - CONF
AU  - Vijatović Petrović, Mirjana
AU  - Bobić, Jelena
AU  - Cilense, Mario
AU  - Zivkovic, Ljiljana
AU  - Stojanović, Biljana
PY  - 2007
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/2658
AB  - Due to its high dielectric constant and low loss characteristics, barium titanate has
been used in many applications, such as capacitors, piezoelectric devices, positive
temperature coelficient thermistors, semiconductors and etc. Doping of BaTi03 ceramics
very irnportant for obtaining very interesting characteristics for various apptications . In this paper it was investigated the effect of doping BaTio3 with La microstructure of BaTiO3 ceramics..
Powders of pure barium titanate and barium titanate doped with 0.3 mol %oLa. in the
presence of small amount of manganese (0.01 mol% Mn), were prepared by polymeric
precursors method through Pechini proccss (soft chemistry) which was carried out as a
three stage process from organometallic complex. Synthesized powders were pressed into
pallets using a cold isostatic press. Sintering was perfomed at 1300 C for 8h (Lenton
furnace, UK). The heating rate was 10'C/min, liith nature cooling in air atmosfere [2]
The X-ray results of samples sintered at 1300 C for 8h prepared fiom pure BaTiO3
powder arld doped BaTiO3 are given on Fig.1. and Fig.2., respectively. It. was approwed that.
pure and doped BaTi03 were lornted as tetragonal crystal structurc.
PB  - 3'd Workshop Nanostructured Materials : Processing and Application September 2, 2007 Bled, Slovenia
C3  - 3'd Workshop Nanostructured Materials : Processing and Application September 2, 2007 Bled, Slovenia
T1  - EFFECT OF LANTHANUM ON MICROSTRUCTURE OF BaTiO3: PREPARED BY POLYMERIC PRECURSORS METHOD
UR  - https://hdl.handle.net/21.15107/rcub_rimsi_2658
ER  - 
@conference{
author = "Vijatović Petrović, Mirjana and Bobić, Jelena and Cilense, Mario and Zivkovic, Ljiljana and Stojanović, Biljana",
year = "2007",
abstract = "Due to its high dielectric constant and low loss characteristics, barium titanate has
been used in many applications, such as capacitors, piezoelectric devices, positive
temperature coelficient thermistors, semiconductors and etc. Doping of BaTi03 ceramics
very irnportant for obtaining very interesting characteristics for various apptications . In this paper it was investigated the effect of doping BaTio3 with La microstructure of BaTiO3 ceramics..
Powders of pure barium titanate and barium titanate doped with 0.3 mol %oLa. in the
presence of small amount of manganese (0.01 mol% Mn), were prepared by polymeric
precursors method through Pechini proccss (soft chemistry) which was carried out as a
three stage process from organometallic complex. Synthesized powders were pressed into
pallets using a cold isostatic press. Sintering was perfomed at 1300 C for 8h (Lenton
furnace, UK). The heating rate was 10'C/min, liith nature cooling in air atmosfere [2]
The X-ray results of samples sintered at 1300 C for 8h prepared fiom pure BaTiO3
powder arld doped BaTiO3 are given on Fig.1. and Fig.2., respectively. It. was approwed that.
pure and doped BaTi03 were lornted as tetragonal crystal structurc.",
publisher = "3'd Workshop Nanostructured Materials : Processing and Application September 2, 2007 Bled, Slovenia",
journal = "3'd Workshop Nanostructured Materials : Processing and Application September 2, 2007 Bled, Slovenia",
title = "EFFECT OF LANTHANUM ON MICROSTRUCTURE OF BaTiO3: PREPARED BY POLYMERIC PRECURSORS METHOD",
url = "https://hdl.handle.net/21.15107/rcub_rimsi_2658"
}
Vijatović Petrović, M., Bobić, J., Cilense, M., Zivkovic, L.,& Stojanović, B.. (2007). EFFECT OF LANTHANUM ON MICROSTRUCTURE OF BaTiO3: PREPARED BY POLYMERIC PRECURSORS METHOD. in 3'd Workshop Nanostructured Materials : Processing and Application September 2, 2007 Bled, Slovenia
3'd Workshop Nanostructured Materials : Processing and Application September 2, 2007 Bled, Slovenia..
https://hdl.handle.net/21.15107/rcub_rimsi_2658
Vijatović Petrović M, Bobić J, Cilense M, Zivkovic L, Stojanović B. EFFECT OF LANTHANUM ON MICROSTRUCTURE OF BaTiO3: PREPARED BY POLYMERIC PRECURSORS METHOD. in 3'd Workshop Nanostructured Materials : Processing and Application September 2, 2007 Bled, Slovenia. 2007;.
https://hdl.handle.net/21.15107/rcub_rimsi_2658 .
Vijatović Petrović, Mirjana, Bobić, Jelena, Cilense, Mario, Zivkovic, Ljiljana, Stojanović, Biljana, "EFFECT OF LANTHANUM ON MICROSTRUCTURE OF BaTiO3: PREPARED BY POLYMERIC PRECURSORS METHOD" in 3'd Workshop Nanostructured Materials : Processing and Application September 2, 2007 Bled, Slovenia (2007),
https://hdl.handle.net/21.15107/rcub_rimsi_2658 .