Despotovic, Zeljko V.

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  • Despotovic, Zeljko V. (1)
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Lead Free (BaZr0.2Ti0.8O3) and Lead Based (PbZr0.52Ti0.48O3) Flexible Thick Films: Structural Properties and Potential Use as Energy Storage and Energy Harvesting Systems

Bobić, Jelena; Ilić, Nikola; Despotovic, Zeljko V.; Džunuzović, Adis; Grigalaitis, Robertas; Stijepovic, Ivan; Vijatović Petrović, Mirjana

(7th World Congress on Materials science and Engineering, 5th World Congress on Lasers, Optics and Photonics, joint event, Valencia, Spain, 2023)

TY  - CONF
AU  - Bobić, Jelena
AU  - Ilić, Nikola
AU  - Despotovic, Zeljko V.
AU  - Džunuzović, Adis
AU  - Grigalaitis, Robertas
AU  - Stijepovic, Ivan
AU  - Vijatović Petrović, Mirjana
PY  - 2023
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/2429
AB  - In the last year energy harvesters based on piezoelectricity from mechanical vibration has emerged as the very promising devices that are explored extensively for its functionality in energy technologies. In this paper a series of flexible lead- free BZT/PVDF and lead based PZT/PVDF piezocomposites with variable filler content up to 50 vol. % have been prepared by hot pressing method. Structure and morphology of BZT and PZT powders as well as distribution of piezo-active filler in obtained flexible films were characterized by XRD and SEM analysis. Total amoun of electro active phase (% FEA) of PVDF is higher in PZT-based films in comparison with BZT based ones but the contribution of more desirable β- phase is higher in BZT-PVDF films. In both composite dielectric permittivity's was increased in contrast to their polymer PVDF host matrix, but also displayed decreased breakdown strenght and raised energy loss. In addition, the remnant polarization (Pr) and leakage current were also investigated to evaluate the breakdown strength in both types of flexible films. Calculations of storage energies and output voltage obtained for the investigated materials revealed an increasing trend with increasing amount of BZT and PZT active phase. The maximum storage energy of 0.42 J/cm3 at 390 kV/cm3 was obtained for PZT-PVDF (40-60) films while the maximum output voltage of about 10 V was obtained for PZT-PVDF (50-50) flexible film. In addition, comparisons between properties of lead based and lead free flexible films as well as potential use of those films as energy storage and energy harvesting systems were considered.
PB  - 7th World Congress on Materials science and Engineering, 5th World Congress on Lasers, Optics and Photonics, joint event, Valencia, Spain
C3  - 7th World Congress on Materials science and Engineering, 5th World Congress on Lasers, Optics and Photonics, joint event, Valencia, Spain
T1  - Lead Free (BaZr0.2Ti0.8O3) and Lead Based (PbZr0.52Ti0.48O3) Flexible Thick Films: Structural Properties and Potential Use as Energy Storage and Energy Harvesting Systems
UR  - https://hdl.handle.net/21.15107/rcub_rimsi_2429
ER  - 
@conference{
author = "Bobić, Jelena and Ilić, Nikola and Despotovic, Zeljko V. and Džunuzović, Adis and Grigalaitis, Robertas and Stijepovic, Ivan and Vijatović Petrović, Mirjana",
year = "2023",
abstract = "In the last year energy harvesters based on piezoelectricity from mechanical vibration has emerged as the very promising devices that are explored extensively for its functionality in energy technologies. In this paper a series of flexible lead- free BZT/PVDF and lead based PZT/PVDF piezocomposites with variable filler content up to 50 vol. % have been prepared by hot pressing method. Structure and morphology of BZT and PZT powders as well as distribution of piezo-active filler in obtained flexible films were characterized by XRD and SEM analysis. Total amoun of electro active phase (% FEA) of PVDF is higher in PZT-based films in comparison with BZT based ones but the contribution of more desirable β- phase is higher in BZT-PVDF films. In both composite dielectric permittivity's was increased in contrast to their polymer PVDF host matrix, but also displayed decreased breakdown strenght and raised energy loss. In addition, the remnant polarization (Pr) and leakage current were also investigated to evaluate the breakdown strength in both types of flexible films. Calculations of storage energies and output voltage obtained for the investigated materials revealed an increasing trend with increasing amount of BZT and PZT active phase. The maximum storage energy of 0.42 J/cm3 at 390 kV/cm3 was obtained for PZT-PVDF (40-60) films while the maximum output voltage of about 10 V was obtained for PZT-PVDF (50-50) flexible film. In addition, comparisons between properties of lead based and lead free flexible films as well as potential use of those films as energy storage and energy harvesting systems were considered.",
publisher = "7th World Congress on Materials science and Engineering, 5th World Congress on Lasers, Optics and Photonics, joint event, Valencia, Spain",
journal = "7th World Congress on Materials science and Engineering, 5th World Congress on Lasers, Optics and Photonics, joint event, Valencia, Spain",
title = "Lead Free (BaZr0.2Ti0.8O3) and Lead Based (PbZr0.52Ti0.48O3) Flexible Thick Films: Structural Properties and Potential Use as Energy Storage and Energy Harvesting Systems",
url = "https://hdl.handle.net/21.15107/rcub_rimsi_2429"
}
Bobić, J., Ilić, N., Despotovic, Z. V., Džunuzović, A., Grigalaitis, R., Stijepovic, I.,& Vijatović Petrović, M.. (2023). Lead Free (BaZr0.2Ti0.8O3) and Lead Based (PbZr0.52Ti0.48O3) Flexible Thick Films: Structural Properties and Potential Use as Energy Storage and Energy Harvesting Systems. in 7th World Congress on Materials science and Engineering, 5th World Congress on Lasers, Optics and Photonics, joint event, Valencia, Spain
7th World Congress on Materials science and Engineering, 5th World Congress on Lasers, Optics and Photonics, joint event, Valencia, Spain..
https://hdl.handle.net/21.15107/rcub_rimsi_2429
Bobić J, Ilić N, Despotovic ZV, Džunuzović A, Grigalaitis R, Stijepovic I, Vijatović Petrović M. Lead Free (BaZr0.2Ti0.8O3) and Lead Based (PbZr0.52Ti0.48O3) Flexible Thick Films: Structural Properties and Potential Use as Energy Storage and Energy Harvesting Systems. in 7th World Congress on Materials science and Engineering, 5th World Congress on Lasers, Optics and Photonics, joint event, Valencia, Spain. 2023;.
https://hdl.handle.net/21.15107/rcub_rimsi_2429 .
Bobić, Jelena, Ilić, Nikola, Despotovic, Zeljko V., Džunuzović, Adis, Grigalaitis, Robertas, Stijepovic, Ivan, Vijatović Petrović, Mirjana, "Lead Free (BaZr0.2Ti0.8O3) and Lead Based (PbZr0.52Ti0.48O3) Flexible Thick Films: Structural Properties and Potential Use as Energy Storage and Energy Harvesting Systems" in 7th World Congress on Materials science and Engineering, 5th World Congress on Lasers, Optics and Photonics, joint event, Valencia, Spain (2023),
https://hdl.handle.net/21.15107/rcub_rimsi_2429 .